O-nitroanisol

Various materials, present by accident or design, can alter the course of reduction by arresting the reaction at an intermediate product or by causing the formation of coupled products (94,95). These deviations can range from only a small yield loss to the formation of a major product. The work of Kosak (56) on o-nitroanisole is instructive in this regard, where small amounts of... 

Benzidine, and the diphenyl bases tolidine and dianisidine which are produced in the same way from o-nitrotoluene and o-nitroanisole, are... 

Titanium ions can also he used as redox catalysts for the indirect cathodic reduction of nitro compounds (417). The electroreduction is carried out in an H20-H2S04/Ti(S04)2-(Pb/Cu) system at 45 80°C under 5 20Am . Nitrobenzene, dinitrobenzene, nitrotoluene, 2,4-dinitrotoluene, 2-nitro-m-xylene, nitro-phenol, 2,4-dinitrophenol, nitrophenetole, o-nitroanisole, 4-nitrochlorotoluene, ni-trobenzenesulfonic acid, and 4,4 -dinitro-stilbene-2,2 -disulfonic acid can all be reduced by this procedure to the corresponding amino compounds (418) in good yields (Scheme 146) [513-516]. Tin... 

Uses Indicator preparation of o-nitroanisole and other organic compounds. 

A total of seven injections of o-nitroanisole in 0.0082-mole increments into a similar solution containing 0.1 mole of NaOH resulted in an average absorption of 496 ml. of H2 per injection. 

Phenyl n-propyl et.her. Phenyl n-butyl ether o-Cresyl methyl ether (1) m-Cresyl methyl ether. p-Cresyl methyl ether. o-Cresyl ethyl ether m-Cresyl ethyl ether p-Cresyl ethyl ether Benzyl methyl ether Benzyl ethyl ether Methyl a-naphthyl ether Methyl p-naphthyl ether Ethyl a-naphthyl ether Ethyl p-naphthyl ether Benzyl a-naphthyl ether Benzyl P-naphthyl ether o-Methoxydiphenyl p-Methoxydiphenyl. o-Chloroanisole. m-Chloroanisole. p-Chloroanisolc o-Bromoanisole m-Bromoanisole. p-Bromoanisole. o-Iodoanisole m-Iodoanisole p-Iodoanisole o-Nitroanisole... 

Fig. I. Polymerization of DL-leucine carbonic anhydride, initiated by preformed polymer. , solvent, nitrobenzene, 45°C X, o-nitroanisole, 45° C O, nitrobenzene, 25.2° C A, o-nitroanisole, 25.0 C. [Reprinted from D. G. H. Ballard and C. H. Bamford Proc. Roy. See. A 223, 495 (1954) (Fig- 4)]...

Aryl iodides. Aryl iodides can be prepared by reaction of arenes with I2 and a mixture of A1C13 and CuCI 2. Yields are moderate to good, but the reaction fails with ethyl benzoate, acetophenone, and o-nitroanisole. The reagents are used in the ratio I2 A1C13 CuCl2 = 0.5 1 1. 

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