Nucleophilic substitution reactions in aqueous solution

Nucleophili substitution, in phosphate esters, mechanism and catalysis of, 25, 99 Nucleophilic substitution, single electron transfer and, 26, 1 Nucleophilic substitution reactions in aqueous solution, 38, 161 Nuckophilic vinylic substitution, 7, 1... [Pg.359]

Solvent effects, reaction coordinates, and reorganization energies on nucleophilic substitution reactions in aqueous solution, 38, 161... [Pg.361]

Short-lived organic radicals, electron spin resonance studies of, 5, 53 Small-ring hydrocarbons, gas-phase pyrolysis of, 4, 147 Solid state, tautomerism in the, 32, 129 Solid-state chemistry, topochemical phenomena in, 15, 63 Solids, organic, electrical conduction in, 16, 159 Solutions, reactions in, entropies of activation and mechanisms, 1, 1 Solvation and protonation in strong aqueous acids, 13, 83 Solvent effects, reaction coordinates, and reorganization energies on nucleophilic substitution reactions in aqueous solution, 38, 161 Solvent, protic and dipolar aprotic, rates of bimolecular substitution-reactions in,... [Pg.409]

Solvent effects, reaction coordinates, and reorganization energies on nucleophilic substitution reactions in aqueous solution, 38, 161 Solvent, protic and dipolar aprotic, rates of bimolecular substitution-reactions in, 5,173 Solvent-induced changes in the selectivity of solvolyses in aqueous alcohols and related mixtures, 27, 239... [Pg.249]

This helped to derive the Hughes-Ingold rules for predicting the effect of solvent polarity on the reaction rate.1 We have used the combined QM-MOVB/MM method to study three nucleophilic substitution reactions in aqueous solution, which are summarized below. [Pg.170]