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Nucleation in polymers

Price F (1969) Nucleation in polymer crystallization. In Zettlemoyer AC (ed) Nucle-ation. Marcel Dekker, Inc, New York... [Pg.182]

Among the numerous challenges faced in understanding polymer crystallization, the present review focuses only on the following issues, which are directly pertinent to the phenomenon of nucleation in polymer crystals. [Pg.3]

NUCLEATION IN POLYMER CRYSTALLIZATION The nucleation part of the linear growth rate is... [Pg.35]

Reimers, J.L., and Schork, F.J., Robust nucleation in polymer-stabilized miniemulsion polymerization, J. Appl. Polym. Sci., 59, 1833-1841 (1996b). [Pg.71]

This concludes the discussion of the nucleation dynamics of macromolecules. It shows that the usually assumed constant number of heterogeneous nuclei and linearly increasing number of homogeneous nuclei is a simplification, and secondary nucleation as the basis for crystal growth is a doubtful concept. Finally, molecular nucleation is not a well enough understood concept to quantitatively explain facts such as the molar mass dependence of crystallization. The further work needed to understand the basis of nucleation in polymers is a big challenge for new research in solid-state polymer science. [Pg.254]


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Nucleation polymers

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