Nuclear reactions uranium series

Transmutation The changing of one element into another by a nuclear reaction or series of reactions. Example the transmutation of uranium-238 into plutonium-239 by absorption of a neutron. 

The second paper of 1940 [3 ], entitled Kinetics of Uranium Chain Decay, is no less significant than the first. This pioneering work yielded a whole series of brilliant results for the first time, the need to take into account the role of delayed neutrons in the kinetics of chain nuclear reactions was shown (it is precisely the delayed neutrons which ensure easy control of nuclear reactors), the influence of heating on the kinetics of a chain process was considered in detail, and a number of conclusions were reached which are of much importance for the theory of reactor control. This same paper predicted the formation in the process of chain fission of new, previously unknown, nuclei which strongly absorb neutrons, a prediction which was later fully confirmed. 

In 1945, Marinsky, Glendenin, and Coryell first identified isotopes of element 61, promethium (Pm), which was the last member of the lanthanide series of rare-earth elements to be discovered. Isotopes of this element were obtained both as products of the fission of uranium and as products of several different types of nuclear reactions, most of which involve suitable bombardment of isotopes of neodymium for example ... 

The nuclear reactions in the uranium-radium series are shown in Figure 3S-2. The principal isotope of uranium, constitutes... 

A series of nuclear reactions that begins with an unstable nucleus and results in the formation of a stable nucleus is called a radioactive decay series. As you can see in Figure 25-11, uranium-238 first decays to thorium-235, which in turn decays to protactinium-234. Decay reactions continue until a stable nucleus, lead-206, is formed. 

Many radionuclides cannot attain nuclear stability by only one nuclear reaction. Instead, they decay in a series of disintegrations. A few such series are known to occur in nature. Two begin with isotopes of uranium, and and one begins with Th. All three of these end with a stable isotope of lead (Z = 82). Table 26-4 outlines in detail the... 

Balance the following equations, which represent nuclear reactions in the uranium-238 decay series. 

Stan is surrounded by nuclear changes that take place outside his body, as well. The soil under his house contains a small amount of uranium-238, which undergoes a type of nuclear reaction called alpha emission. A series of changes in the nucleus of the uranium-238 leads to an even smaller amount of radon-222, which is a gas that he inhales in every breath he takes at home. Subsequently, radon-222 undergoes a nuclear reaction very similar to the reaction for uranium-238. 

The disintegration of a radioactive nucleus is often the beginning of a radioactive decay series, which is a sequence of nuclear reactions that ultimately result in the formation of a stable isotope. Table 23.3 shows the decay series of naturally occurring uranium-238, which involves 14 steps. This decay scheme, known as the uranium decay series, also shows the half-lives of all the products. 

It is important to be able to balance the nuclear reaction for each of the steps in a radioactive decay series. For example, the first step in the uranium decay series is the decay of uranium-238 to thorium-234, with the emission of an a particle. Hence, the reaction is... 

Nuclei differ in their stability, and some are so unstable that they undergo radioactive decay. The ratio of the number of neutrons to number of protons (N/Z) in a nucleus correlates with its stability. Calculate the N/Z ratio for (a) Sm (b) Fe (c) °Ne (d) ° Ag. (e) The radioactive isotope decays in a series of nuclear reactions that includes another uranium isotope, and three lead isotopes, Pb, °Pb, and ° Pb. How many neutrons, protons, and electrons are in each of these fi ve isotopes ... 

Some nuclei cannot gain stability by a single emission. Consequently, a series of successive emissions occurs as shown for uranium-238 in A FIGURE 21.3. Decay continues until a stable nucleus—lead-206 in this case—is formed. A series of nuclear reactions that begins with an unstable nucleus and terminates with a stable one is known as a radioactive series or a nuclear disintegration series. Three such series occur in nature uranium-238 to lead-206, uranium-235 to lead-207, and thorium-232 to lead-208. 

Another major turning point in the history of nuclear science came with the discovery of fission by Otto Hahn and Fritz Strassmann in December 1938 (Hahn and Strassmann 1939a, b). In several laboratories in Rome, Berlin, and Paris, a complex series of P-decay chains resulting from neutron irradiation of uranium had been investigated since 1934, and these chains had been assigned to putative transuranium elements formed by neutron capture in uranium with subsequent P" transitions increasing the atomic numbers (see Sect. 1.2.3). But then evidence appeared that known elements in the vicinity of uranium, such as radium, were produced as well. When Hahn and Strassmaim attempted to prove this by a classical fractional crystallization separation of radium from barium serving as its carrier, the radioactivity turned out to be barium, not radium hence, new and totally unexpected type of nuclear reaction had to be invoked. 

Radioactive nuclei emit a particles, 13 particles, positrons, or y rays. The equation for a nuclear reaction includes the particles emitted, and both the mass numbers and the atomic numbers must balance. Uranium-238 is the parent of a natural radioactive decay series. A number of radioactive isotopes, such as and C, can be used to date objects. Artificially radioactive elements are created by the bombardment of other elements by accelerated neutrons, protons, or a particles. Nuclear fission is the splitting of a large nucleus into smaller nuclei plus neutrons. When these neutrons are captured efficiently by other nuclei, an uncontrollable chain reaction can occur. Nuclear reactors use the heat... 

The seventh period begins, as do others, with an alkali metal and an alkaline earth. Thorium (Th) begins a series of 14 actinide elements corresponding to the actinides. All of these elements are radioactive, and those beyond uranium (U) do not occur in nature, at least not in appreciable quantities. Rather, they are all artificially made via nuclear reactions. They are among the products of modern atomic research, and their names refer to the places (Berkeley and California) and the people (Fermi and Lawrence) involved. 

Uranium is best known as a fuel for nuclear power plants. To prepare this fuel, uranium ores are processed to extract and enrich the uranium. The process begins by mining uranium-rich ores and then crushing the rock. The ore is mixed with water and thickened to form a slurry. The slurry is treated with sulfuric acid and the product reacted with amines in a series of reactions to give ammonium diuranate, (NH4)2U20 . Ammonium diuranate is heated to yield an enriched uranium oxide solid known as yellow cake. Yellow cake contains from 70—90% U3Og in the form of a mixture of U02 and U03. The yellow cake is then shipped to a conversion plant where it can be enriched. 

The discovery in 1938-1939 of nuclear fission of uranium, which led ultimately to the discovery of nuclear power, heralded a new, extraordinarily fruitful stage in Ya.B. s scientific activity. His interests were concentrated on the study of the mechanism of fission of heavy nuclei and, what proved particularly important, on the development of a theory of the chain fission reaction of uranium. During 1939-1943 Ya.B. wrote several papers which laid the foundation for this subject and were of fundamental value. We note that four of these papers, written in collaboration with Yu. B. Khariton, were done practically in two years before the war. The papers of this series form the foundation of modern physics of reactors and nuclear power they are widely known and do not require special commentary—a short review of the basic physical results is eloquent enough. 

Burger, L.L. 1958. The decomposition reactions of tributyl phsophate and its diluents and their effect on uranium recovery processes. Progress in Nuclear Energy Series HI Pergamon Press London, Process Chemistry, Vol. 2, 7-5, 307-319. 

Actinides in the environment can be classified into two groups (i) the uranium and thorium series of radionuclides in the natural environment and (ii) neptunium, plutonium, americium and curium which are formed in a nuclear reactor during the neutron bombardment of uranium through a series of neutron capture and radioactive decay reactions. Transuranics thus produced have been spread widely in the atmosphere, geosphere and aquatic environment on the earth, as a result of nuclear bomb tests in the atmosphere, and accidental release from nuclear facilities (Sakanoue, 1987). Most of these radionuclide inventories have deposited in the northern hemisphere following the tests conducted by the United States and the Soviet Union. 

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