Nuclear magnetic resonance transition metals

Granger, P. In Transition Metal Nuclear Magnetic Resonance Pregosin, P. S., Ed., Elsevier Amsterdam 1991 pp 288-345. 

There is an approximately linear relationship between Rv and spin transfer coefficients determined from electron and nuclear magnetic resonance and neutron diffraction, i.e., a contraction of the unit cell accompanies the transfer of spin from transition metal to the ligands. 

P.S. Pregosin (Ed.), Transition Metal Nuclear Magnetic Resonance, Elsevier, Amsterdam, 1991. 

Nuclear magnetic resonance (NMR) measurements are usually considered to be slow processes, but recent advances in the design of flow-through NMR cells have allowed the method to be applied in combinatorial chemistry 97). These technological improvements were applied to the development of two NMR-based high-throughput ee assays for evaluating the products of enzyme- or transition metal-catalyzed reactions 98). 

In the last few years, DFT has also become one of the prime methods for the study of nuclear magnetic resonance (NMR) chemical shifts in transition metal complexes and other large molecules. DFT calculations of NMR chemical shifts have been reviewed (3,4). 

Green, M.L.H., Hughes, A.K., Popham, N.A., Stephens, A.H.H. and Wong, L.L. (1992) Nuclear magnetic resonance studies on partially deuteriated transition metal—methyl derivatives. /. Chem. Soc., Dalton Trans., 3077. 

Vrieze, K. and van Leeuwen, P. W. N. M., Studies of Dynamic Organometallic Compounds of the Transition Metals by Means of Nuclear Magnetic Resonance. 14 1... 

Included for the first time in this section are books and surveys on spectroscopic techniques which are of great use to the organometallic chemist. In addition to the Chemical Society Specialist Periodical Reports on Spectroscopic Properties of Inorganic and Organometallic Compounds (B6.1) and Mass Spectrometry (B6.2), a series of Annual Reviews (volumes 1 or 2) or Reports (volume 3 onwards) on Nuclear Magnetic Resonance Spectroscopy contains surveys of or P NMR results appertaining to organo-transition metal complexes. 

R. Fields Fluorine-19 Nuclear Magnetic Resonance Spectroscopy, pp. 99-304 (513), esp. pp. 255 -286, Transition metal complexes of fluorinated molecules. 

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