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Nuclear magnetic resonance spectra fluorine

Fox et al. (9 ) also investigated the nuclear magnetic resonance spectrum of NOFg which indicated that the molecule contained three equivalent fluorine atoms. This result, along with the general appearance of the infrared spectrum, clearly establishes that the molecule has Cg symmetry. The N-0 bond distance and bond angles are estimated quantities from the work of Curtis et al. (7 ). [Pg.1123]

If one wishes to obtain a fluorine NMR spectrum, one must of course first have access to a spectrometer with a probe that will allow observation of fluorine nuclei. Fortunately, most modern high field NMR spectrometers that are available in industrial and academic research laboratories today have this capability. Probably the most common NMR spectrometers in use today for taking routine NMR spectra are 300 MHz instruments, which measure proton spectra at 300 MHz, carbon spectra at 75.5 MHz and fluorine spectra at 282 MHz. Before obtaining and attempting to interpret fluorine NMR spectra, it would be advisable to become familiar with some of the fundamental concepts related to fluorine chemical shifts and spin-spin coupling constants that are presented in this book. There is also a very nice introduction to fluorine NMR by W. S. and M. L. Brey in the Encyclopedia of Nuclear Magnetic Resonance.1... [Pg.21]

Fullerenes can be derivatized by various means. For example, reaction with fluorine gas proceeds stepwise to the formation of colorless CeoFeo, which, according to the 19F nuclear magnetic resonance (NMR) spectrum, contains just one type of F site and so evidently retains a high degree of symmetry.9 In view of the low adhesion typical of fluorocarbons, this spherical molecule is expected to have extraordinary lubricant properties. Curiously, bromination of Ceo is reversible on heating otherwise, the reactions of fullerenes resemble those of alkenes or arenes (aromatic hydrocarbons). [Pg.57]

Evidence that the proton lies midway between the fluorine atoms in the crystal KHF has been provided by entropy measurements,28 study of the polarized infrared spectrum,29 neutron diffraction,80 and nuclear spin magnetic resonance.81 The uncertainty in the location of the proton at the midpoint between the fluorine atoms is reported to be 0.10 A for the neutron diffraction study and 0.06 A for the nuclear magnetic resonance study. [Pg.461]

The magnetic resonance spectrum of HF was studied some nine years earlier than the electric resonance spectrum by Baker, Nelson, Leavitt and Ramsey [93] in this case the transitions studied were magnetic dipole, corresponding to reorientation of the proton and fluorine nuclear spins. Values of the nuclear spin rotation and dipolar constants were essentially confirmed by the later electric resonance measurements. We now describe measurements of the electric resonance spectrum in the additional presence of a strong magnetic field, carried out by de Leeuw and Dymanus [89]. [Pg.496]


See other pages where Nuclear magnetic resonance spectra fluorine is mentioned: [Pg.313]    [Pg.184]    [Pg.187]    [Pg.332]    [Pg.3]    [Pg.421]    [Pg.101]    [Pg.418]    [Pg.533]    [Pg.165]    [Pg.63]    [Pg.246]    [Pg.246]    [Pg.282]   
See also in sourсe #XX -- [ Pg.19 , Pg.338 ]




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