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Nuclear magnetic resonance detecting apparatus

Tor reference. Positive identification can be made only by collecting the compound or transierring it as it elutes directly into another apparatus for analysis by other means, such as infrared or ultraviolet spectroscopy, mass spectrometry, or nuclear magnetic resonance. Commercially available apparatus is available which combines in a single unit both a gas chromatograph and an infrared, ultraviolet, or mass spectrometer for routine separation and identilicalion. The ancillary system may also be microprocessor-based, with an extensive memory for storing libraries of known infrared spectra or fragmentation patterns (in the case of mass spectrometers). Such systems allow microprocessor-controlled comparison and identilicalion of detected compounds. [Pg.378]

An important issue associated with molecular machines is the detection of actuations on the nanoscale level. When a chemical stimulus induces movement in a machine, several spectroscopic techniques, such as nuclear magnetic resonance (NMR) spectroscopy, UV-Vis spectroscopy, emission spectroscopy and X-ray photoelectron spectroscopy (XPS) can be used to detect their outputs. More intri-guingly, electrochemical and photochemical inputs often provide [6, 8g] a two-fold advantage by inducing the mechanical movements and detecting them. Additionally, the dual actions of the these two types of stimuli can be exploited when the time-scale of the molecular actuations, which ranges from picoseconds to seconds, falls within the detection time-scale of the apparatus. [Pg.296]


See other pages where Nuclear magnetic resonance detecting apparatus is mentioned: [Pg.6]    [Pg.649]    [Pg.429]    [Pg.224]    [Pg.427]    [Pg.383]    [Pg.572]    [Pg.250]    [Pg.11]    [Pg.210]    [Pg.11]    [Pg.64]    [Pg.42]    [Pg.167]   


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