Trichloro--nonane

N-Nitroso N phenylglycine, 46, 96 reaction with acetic anhydride to yield 3 phenylsydnone, 46, 96 Nitrosyl chloride, addition to bicyclo-[2 2 ljhepta 2,5 diene, 46, 75 2,4-Nonanedione, 47, 92 Nonane, 1,1,3 trichloro-, 46,104 Nortricyclanol, 46, 74 oxidation by chromic acid, 46, 78 Nortricyclanone, 46, 77 Nortncj clyl acetate 46, 74 frombicyclo[2 2 ljhepta 2,5 dieneand acetic acid, 46, 74 saponification of, 46, 75... 

Diethylammonium chloride, reaction with chloroform to give 1,1,3-trichloro- -nonane, 45,104 Diethylazelate, 46, 31 Diethylbenzene as solvent for decomposition of diphenyliodonium-2-carboxylate in preparation of... 

A related reaction is the addition of l,l,2-trichloro-2-nitrosoethene to the oxepin/benzene oxide mixture. The primary adduct cannot be isolated but the rearrangement product 9-(tri-chlorovinyl)-tra . -3,6-dioxa-9-azatetracyclo[6.1.0.0z,4.05,7]nonane (6) is obtained in 17% yield.221... 

Trichloroacetyl fluoride, 45, 6 2-(Trichloromethyl)bicyclo[3.3.0]octane, from reaction of chloroform and cib,o i-l,5-cyclooctadiene, 47,10 hydrolysis with phosphoric acid to c.ro-m-bicyclo[3.3.0]octane-2-carboxylic acid, 47, 11 1,1,3-Trichloro- -nonane, 46,104 Tricyclo[2.2.1,02 6]heptan-3-ol, 46,... 

A solution of 0.54 g. (2 mmoles) of ferric chloride hexahydrate and 0.33 g. (3 mmoles) of diethylammonium chloride (Note 1) in 5 g. of methanol is added to a solution of 11.2 g. (0.1 mole) of 1-octene (Note 2) and 0.42 g. (2 mmoles) of benzoin (Note 3) in 36 g. (0.3 mole) of chloroform (Note 4). The resulting homogeneous mixture is introduced into a Carius tube of about 100-ml. capacity. Air is displaced by dropping a few pieces of dry ice into the tube (Note 5). The tube is sealed (Note 6), heated to 130°, kept at that temperature for 15 hours, cooled to room temperature (Note 7), and opened. The contents of the tube are transferred to a separatory fuimel, and the tube is rinsed with about 10 ml. of chloroform. The reaction mixture is washed with 40 ml. of water. The aqueous solution is extracted with 10 ml. of chloroform, and the extract is added to the original chloroform layer. Solvent is distilled at atmospheric pressure (bath temperature up to 130°). The distillation flask is allowed to cool, and distillation is continued at 25 mm. (bath temperature up to 120°) (Note 8). The flask is cooled again, and distillation is continued to dryness at 0.1 mm. (bath temperature up tc 150°), giving crude l,l,3-trichloro- -nonane (19.4 g.) as a yellow oil, b.p. 60-85° (0.1 mm.), 1.4650. The purity of this... 

Benzene, bromoethynxl, 46, 86 Benzenesulfonic anhydride, 45, 88 Benzoin, reaction with chloroform to give l,l,3-trichloro- -nonane, 46, 104... 

By repeated distillation of fraction II we isolated 9 g of 3,5-Dichloro-2-nonene (11.8% of theor.) From fraction II we isolated 16.9 g (18.8%) of 3,3,5-Trichloro-nonane. 

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