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Non-equilibrium thermal

Since the size of the laser beam is large compared to the laser penetration depth, the short-pulse laser heating of materials can be modeled as one-dimensional. A set of consistent models for the non-equilibrium thermal system is composed of two parts, one of which is tiie eerier tiansport equation and the other the lattice one as follows [17, 20] ... [Pg.293]

Non-Equilibrium Thermal Conductivity and Treanor Effect in Vibrational Energy Transfer... [Pg.112]

Other sources of adsorption energies are the TDS-related adsorption desorption transient (ADT) and adsorption desorption equilibrium (ADE) measmements which can equally be extrapolated to the zero-coverage limit [84Baul]. Differences in TDS- and ADE-derived ads(0 ML)-values are often ascribed to a barrier to desorption which manifests itself only in the inherently non-equilibrium thermal desorption process, but not in the quasi-equilibrium isosteric heat of adsorption obtained from ADE [92Kim]. [Pg.220]

To this we follow closely Baym and Baym and Kadanoff in their discussion of perturbation theory for non-uniform systems. They consider non-equilibrium thermal Green s functions at an arbitrary temperature B in the presence of an external, in general non-local potential U that acts in the imaginary time interval O < it < 6. Writing the operators in the interaction representation for the external disturbance, the one-particle Green s function is... [Pg.124]

Considerable interest is being shown in differential thermal analysis and differential scanning calorimetry, but more work is required to examine the accuracy of results obtained with these non-equilibrium thermal techniques. [Pg.55]

The kinds of substitution mechanisms that may be relevant to super-low concentration elements such as Pa involve intrinsic defects, such as lattice vacancies or interstitials. Vacancy defects can potentially provide a low energy mechanism for heterovalent cation substitution, in that they remove or minimise the need for additional charge balancing substitutions. Formation of a vacancy per se is energetically unfavourable (e.g., Purton et al. 1997), and the trace element must rely instead on the thermal defect concentration in the mineral of interest, at the conditions of interest. Extended defects, such as dislocations or grain boundaries, may also play a key role, but as these are essentially non-equilibrium features, they will not be considered further here. [Pg.84]

Chyu, M. C., 1989, Formation and Heat Transfer Mechanism of Vapor Mass during Nucleate Boiling, in Thermal, Non-equilibrium in Two-Phase Flow, pp. 157-181, ENEA, Rome. (2)... [Pg.527]

Forslund, R. P, and W. M. Rohsenow, 1966, Thermal Non-Equilibrium in Dispersed Flow Film Boiling in a Vertical Tube, MIT Heat Transfer Lab. Rep. 75312-44, Massachusetts Institute of Technology, Cambridge, MA. (4)... [Pg.533]

Groeneveld, D. C., G. G. J. Delorme, 1976, Prediction of Thermal Non-equilibrium in the Post Dryout Regime, Nuclear Eng. Design 36 17-26. (4)... [Pg.535]

The glass transition involves additional phenomena which strongly affect the rheology (1) Short-time and long-time relaxation modes were found to shift with different temperature shift factors [93]. (2) The thermally introduced glass transition leads to a non-equilibrium state of the polymer [10]. Because of these, the gelation framework might be too simple to describe the transition behavior. [Pg.206]

Since the discovery of the parton substructure of nucleons and its interpretation within the constituent quark model, much effort has been spent to explain the properties of these particles and the structure of high density phases of matter is under current experimental investigation in heavy-ion collisions [17]. While the diagnostics of a phase transition in experiments with heavy-ion beams faces the problems of strong non-equilibrium and finite size, the dense matter in a compact star forms a macroscopic system in thermal and chemical equilibrium for which effects signalling a phase transition shall be most pronounced [8],... [Pg.416]

The theory of nuclear spin relaxation (see monographs by Slichter [4], Abragam [5] and McConnell [6] for comprehensive presentations) is usually formulated in terms of the evolution of the density operator, cr, for the spin system under consideration from some kind of a non-equilibrium state, created normally by one or more radio-frequency pulses, to thermal equilibrium, described by Using the Bloch-Wangsness-Redfield (BWR) theory, usually appropriate for the liquid state, we can write [7, 8] ... [Pg.328]

Within non-equilibrium thermodynamics, the driving force for relaxation is provided by deviations in the local chemical potential from it s equilibrium value. The rate at which such deviations relax is determined by the dominant kinetics in the physical system of interest. In addition, the thermal noise in the system randomly generates fluctuations. We thus describe the dynamics of a step edge by the equation. [Pg.17]

In the previous chapter self-organization was shown to have a very strong component in the domain of physics of non-linear systems, and actually some examples of self-organization in non-equilibrium systems have already been given, such as the beehive structure in silicon oil subjected to thermal gradient. This should be repeated at the level of emergence. [Pg.120]

Several techniques are available for thermal conductivity measurements, in the steady state technique a steady state thermal gradient is established with a known heat source and efficient heat sink. Since heat losses accompany this non-equilibrium measurement the thermal gradient is kept small and thus carefully calibrated thermometers and heat source must be used. A differential thermocouple technique and ac methods have been used. Wire connections to the sample can represent a perturbation to the measurement. Techniques with pulsed heat sources (including laser pulses) have been used in these cases the dynamic response interpretation is more complicated. [Pg.656]


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