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Nitroso compound aliphatic

NITROSO COMPOUNDS AlIphat i c and Ali cyclic Aromatic N i trosamines... [Pg.647]

Similarly to nitroso compounds, aliphatic and aromatic hydrazines, as well as hydrazides, react with sodium pentacyanoammoferroate (79). [Pg.373]

Tertiary aliphatic - aromatic amines, unlike those of the aliphatic series, react with nitrous acid with the formation of G-nitroso compounds the nitroso group enters almost exclusively in the para position if available, otherwise in the ortho position. Thus dimethylaniline yields />-nitrosodiniethylaniline ... [Pg.562]

With a peroxyacid, the reagent used in their preparation, oxaziridines further react to yield aliphatic nitroso compounds. An electrophilic attack to ring nitrogen is plausible, leading to an intermediate oxaziridine N-oxide (81), which immediately decomposes to a nitroso compound and an aldehyde (57JA6522). [Pg.207]

Aliphatic nitroso compounds are obtained either by hypobromite oxidation of alkylhy-droxylamines made by oxaziridine hydrolysis, or directly from oxaziridines by action of a second mole of peracid (Section 5.08.3.1.3). [Pg.235]

The yields of the dimeric nitroso compounds are good. Thus the aliphatic nitroso compounds which previously were difficult to obtain become readily available. A series of dimeric nitroso compounds with primary and secondary alkyl groups are given in Table III. [Pg.103]

Aromatic nitro compounds are hydrogenated very easily aliphatic nitro compounds considerably more slowly. Hydrogenations have been carried out successfully under a wide range of conditions including vapor phase (S9). Usually the goal of reduction is the amine, but at times the reduction is arrested at the intermediate hydroxylamine or oxime stage nitroso compounds never accumulate, although their transient presence may appreciably influence the course of reaction. In practice, nitro compounds often contain other reducible functions that are to be either maintained or reduced as well. [Pg.104]

The reaction of secondary amines with aqueous nitrous acid generates /V-nitroso compounds (Eq. 11.5). Such a nitrosation occurs with both aromatic and aliphatic secondary amines.6... [Pg.342]

A general method for nitrone formation is based on the interaction of nitro compounds with carbanions. Interaction between nitroso compounds (175) and anions of aliphatic nitro compounds (178) leads to nitrones (179). The source of anions are metal salts of nitro compounds, triethylamines, and trimethylsilylni-tronates (Scheme 2.63) (334, 335). [Pg.178]

N-Hydroxy-N-nitrosamines with an aliphatic group at O2 produce a compound stable to aqueous acid and base (Fig. 3.4, 29) [158], whereas all other N-hydroxy-N-nitrosamines are susceptible to hydrolysis and appropriate 02-derivatives also render these materials vulnerable. The hydrolysis endpoint is the formation of nitroxyl (HNO) [which dimerizes to form nitrous oxide (N20)] and a C-nitroso compound. These products are formed from aryl [159] and alkyl bound unsubstituted diazenium-diolates as well as Oralkylated derivatives [160]. Studies of the solvolysis of Oi-alkyl derivatives are complicated by their tendency to decompose via competing radical pathways [161], but the Oi-benzyl derivatives are unique in that they hydrolyze back to the original synthetic precursors (Scheme 3.14) [162]. [Pg.70]

Alkyl and aryl C-nitroso compounds contain a nitroso group (-N=0) directly attached to an aliphatic or aromatic carbon. As compounds with a nitroso group attached to a primary or secondary carbon exist primarily as the oxime tautomer, the stable examples of C-nitroso compounds contain nitroso groups attached to tertiary carbons, such as 2-methyl-2-nitroso propane (1, Fig. 7.1) or nitroso groups attached to carbons bearing an electron-withdrawing group (-CN, -N02, -COR, -Cl, -OAc, Fig. 7.1). Oxidation of alkyl and aryl hydroxylamines provides the most direct route to alkyl and... [Pg.177]

Apart from rare exceptions, the only nitroso-compounds known are those in which the NO-group is united to a tertiary carbon atom, as in nitrosobenzene. Nitrosoisobutane (H3C)3 C.NO, for example, is a representative from the aliphatic series. [Pg.180]

The Hel PE spectrum of nitrosomethane (Figure 13) was first studied by Bergmann and Bock125,127. This compound as well as several other aliphatic and aromatic C-nitroso compounds were investigated by Pfab and coworkers126,128, however several of them were dimers. [Pg.188]

Joel F. Liebman, Mary Stinecipher Campbell and Suzanne W. Slayden D. Aliphatic Nitroso Compounds... [Pg.360]

Nitroso derivatives (with the nitroso group bound to a carbon atom) can exist in three molecular forms176177 the monomer 63 and the dimers 64 and 65, Z and E, respectively. Aliphatic C-nitroso compounds are mainly dimers178. Aromatic nitroso derivatives, in solution, may be monomers or dimers, depending on the concentration and temperature, and on the substituent on the aromatic ring. Nitrosobenzene itself is in the E dimer form in the solid state179. [Pg.447]

This chapter presents a selective account of advances in the chemistry of amino and nitro compounds since the appearance of previous volumes in this seriesla-d. The emphasis in the section on nitro compounds is on aliphatic members of this class. The original plan to include a review of nitroso compounds was abandoned when it was found that there had not been sufficiently important developments in this area in the last 26 years. However, specific aspects of nitroso compounds are treated in this volume in the chapters by D. L. H. Williams, by A. H. Mehles and by P. Eyer and D. Galleman. [Pg.534]

IV. RADIOLYSIS OF NITRO AND NITROSO COMPOUNDS A. Aliphatic Nitro Compounds... [Pg.832]

Aliphatic nitro compounds exhibit rather different behavior from nitroaromatic compounds. Secondary and primary nitro compounds tend to produce oximes because the intermediate nitroso compound quickly tautomerizes to the oxime (equation 1). Under aprotic conditions the radical anions of primary and secondary nitro compounds are relatively stable those derived from tertiary nitro compounds, on the other hand, eject nitrite ion relatively readily (equation 2)8. [Pg.839]

The major route of formation of these nitro compounds is via the reaction of VOCs with the NO arising from hot flue gases, such as automobile exhaust gases and gas streams used for drying food stuffs, etc. In these combustion systems the aliphatics can react with nitro compounds or arenes to produce nitro-PAH and nitroarenes. Some of the NO produced are thus converted into C-nitroso compounds. The interactions and reaction chemistry of these compounds is complex and difficult to interpret. [Pg.1174]

Aliphatic nitro compounds with the nitro group on a tertiary carbon were reduced to amines with aluminum amalgam [146 or iron [559]. 2-Nitro-2-methylpropane afforded ferf-butylamine in 65-75% yield [146. Even some secondary nitroalkanes were hydrogenated to amines. fra s-l,4-Dinitrocy-clohexane was converted to frans-l,4-diaminocyclohexane with retention of configuration. This may be considered as an evidence that the intermediate nitroso compound is reduced directly and not after tautomerization to the isonitroso compound [560] (see Scheme 54). [Pg.69]

An overall strategy for the synthesis of 1,2,5-thiadiazoles from the acyclic N-C-C-N grouping and sulfur monochloride was proposed in 1967 (1967JOC2823). The N-C function could vary over oxidation levels of amine, imine, cyanide, oxime and nitroso derivatives. Aliphatic and aromatic compounds having these functionalities in many combinations reacted with sulfur monochloride to form appropriately substituted or fused 1,2,5-thiadiazoles. Based on this model, a large... [Pg.180]


See other pages where Nitroso compound aliphatic is mentioned: [Pg.711]    [Pg.711]    [Pg.711]    [Pg.711]    [Pg.711]    [Pg.711]    [Pg.711]    [Pg.711]    [Pg.198]    [Pg.847]    [Pg.1539]    [Pg.175]    [Pg.176]    [Pg.89]    [Pg.60]    [Pg.178]    [Pg.62]    [Pg.202]    [Pg.51]    [Pg.4]    [Pg.191]    [Pg.338]    [Pg.579]    [Pg.1171]    [Pg.379]   


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Aliphatic compounds

Aliphatics compounds

Nitroso compounds

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