Thermodynamic properties nitrogen

Sage, B. H., Lacey, W. N., "Thermodynamic Properties of Higher Paraffin Hydrocarbons and Nitrogen," Am. Petr. Inst., New York, N.Y. (1950). ... 

The increasing ranges of pressure and temperature of interest to technology for an ever-increasing number of substances would necessitate additional tables in this subsection as well as in the subsec tion Thermodynamic Properties. Space restrictions preclude this. Hence, in the present revision, an attempt was made to update the fluid-compressibihty tables for selected fluids and to omit tables for other fluids. The reader is thus referred to the fourth edition for tables on miscellaneous gases at 0°C, acetylene, ammonia, ethane, ethylene, hydrogen-nitrogen mixtures, and methyl chloride. The reader is also... 

Since air is a mixture of predominantly nitrogen, oxygen, and a host of lesser impurities, there has been less interest in developing precise thermodynamic properties. The only recent correlation of thermodynamic properties is that published by Vasserman, et al. (Barouch, Israel Program for Scientific Translations, Jerusalem, 1970), and is based on the principle of corresponding states because of the scarcity of experimental data. 

Computes thermodynamic properties of air, argon, carbon monoxide, carbon dioxide, hydrogen, nitrogen, oxygen, water vapor, and products of combustion for hydrocarbons. Computes all properties from any two independent properties. 

In the previous discussion of laminar and turbulent flames, the effects of the physical and chemical parameters on flame speeds were considered and the trends were compared with the experimental measurements. It is of interest here to recall that it was not possible to calculate these flame speeds explicitly but, as stressed throughout this chapter, it is possible to calculate the detonation velocity accurately. Indeed, the accuracy of the theoretical calculations, as well as the ability to measure the detonation velocity precisely, has permitted some investigators to calculate thermodynamic properties (such as the bond strength of nitrogen and heat of sublimation of carbon) from experimental measurements of the detonation velocity. 

Thermodynamic properties for explosion calculations are presented for major organic chemical compounds. The thermodynamic properties include enthalpy of formation, Gibbs free energy of formation, internal energy of formation and Helmholtz free energy of formation. The major chemicals include hydrocarbon, oxygen, nitrogen, sulfur, fluorine, chlorine, bromine, iodine and other compound types. 

Homogeneous Liquids. The physical properties important in determining the suitability of a liquid for propellant application are the freezing point, vapor pressure, density, and viscosity. To a lesser extent, other physical properties are important such as the critical temperature and pressure, thermal conductivity, ability to dissolve nitrogen or helium (since gas pressurization is frequently used to expel propellants) and electrical conductivity. Also required are certain thermodynamic properties such as the heat of formation and the heat capacity of the material. The heat of formation is required for performing theoretical calculations on the candidate, and the heat capacity is desired for calculations related to regenerative cooling needs. 

The very low value of Ashmore and Burnett is difficult to explain. It is easy to demonstrate that the discrepancy is not resolved by assuming the N03 intermediate in nitrogen dioxide decomposition is the pernitrite radical, in contradistinction to the symmetric nitrate radical. Their calculation of k5 depended on an experimentally obtained value for k 5 and an equilibrium constant K5- 5 calculated from thermodynamic properties for N03 measured by Schott and Davidson and Ray and Ogg. These results, obtained in a nitrogen pentoxide system, pertain to the nitrate radical, not the pernitrite radical. Guillory and Johnston176 reported an equilibrium constant based on estimated... 

Sage, B.H. and Lacey, W.N. Thermodynamic Properties of the Lighter Paraffin Hydrocarbons and Nitrogen, Monograph on API Research Project 37, API, New York (1950). 

Matrix isolation methods of synthesis have also been used to prepare and study coordination compounds. These involve the vaporization of a metal and a potential ligand, which are then rapidly carried in a stream of inert gas to a very cold surface, where the compound which has been formed is quickly trapped in the solid matrix. It is possible to determine the type of bonding, the structure and the thermodynamic properties of the compounds formed. Only small ligand molecules have been used thus far carbon monoxide, nitric oxide, nitrogen and oxygen, for example, but molecules of great interest have been formed. Some such are [Pd(C2H4)], [Pd(N2)3], [Ni(N2)202], [Ni(N2)4] and [Ni(CO)(N2)3].41... 

Heats of formation assume resonance stabilizations 10.8 kcal mole-1 in ( CHaCN) 12.6 kcal mole-1 in (CH3CHCN) and in [(CH3)2CCN]. " Na = doubly bonded nitrogen in azo compounds. h This correction assumes that the barrier to rotation in the radical R is two-thirds the barrier in the corresponding alkane RH. See O Neal and Benson for further discussion of this point. AH° and to +2 cal mole-1 °K 1 for 5°. The following example shows how the table is used to calculate thermodynamic properties for the 2-butyl radical (12).41 H3C—ch—ch2—ch3 12 ... 

E. S. Domalski and E. D. Hearing,/. Phys. Chem. Ref. Data, 22, 805 (1993). Estimation of the Thermodynamic Properties of Carbon-Hydrogen-Nitrogen-Oxygen-Sulfur-Halogen Compounds at 298.15 K. 

Jacobson, R.T. and Stewart, R.B., Thermodynamic properties of nitrogen including liquid and vapor phases from 63 K to 2000 K with pressures to 10,000 bar, J. Phys. Chem. Ref. Data, 2, 757, 1973. 

Inverse gas chromatography (IGC) is another technique that can be used to measure the specific surface area of a particulate material, as well as to measure a number of surface thermodynamic properties of powders. Such instrumentation operates on a different principle than traditional nitrogen/krypton adsorption using the BET isotherm. 

L. V. Gurvich, I. V. Veyts, and C. B. Alcock, Thermodynamic Properties of Individual Substances, Vol. 1 Elements Oxygen, Hydrogen (Deuterium, Tritium), Fluorine, Chlorine, Bromine, Iodine, Helium, Neon, Argon, Krypton, Xenon, Radon, Sulfur, Nitrogen, Phosphorus, and Their Compounds, Pt. 1 Methods and Computation, Hemisphere, New York, 1989. 

TABLE 2. Thermodynamic properties of connections of titanium with oxygen, nitrogen, hydrogen... 

The heat capacity of thiazole was determined by adiabatic calorimetry from 5 to 340°K by Goursot and Westrum (295,296). A glass-type transition occurs between 145 and 175 K. Melting occurs at 239.53°K (-33.62°C) with an enthalpy increment of 2292 cal mole" and an entropy increment of 9.57 cal mole" -"K". Table 1-44 summarizes the variations as a function of temperature of the most important thermodynamic properties of thiazole molar heat capacity Cp, standard entropy S°, and Gibbs function -(G°-The variation of Cp for crystalline thiazole between 145 and 175°K reveals a marked inflection that has been attributed to a gain in molecular freedom within the crystal lattice. The heat capacity of the liquid phase varies nearly linearly with temperature to 310°K, at which temperature it rises more rapidly. This thermal behavior, which is not uncommon for nitrogen compounds, has been attributed to weak intermolecular association. The remarkable agreement of the third-law ideal-gas entropy at... 

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