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Nitrogen diatomic

The advantages of INDO over CNDO involve situations where the spin state and other aspects of electron spin are particularly important. For example, in the diatomic molecule NH, the last two electrons go into a degenerate p-orbital centered solely on the Nitrogen. Two well-defined spectroscopic states, S" and D, result. Since the p-orbital is strictly one-center, CNDO results in these two states having exactly the same energy. The INDO method correctly makes the triplet state lower in energy in association with the exchange interaction included in INDO. [Pg.279]

Water-soluble sdanols such as (1) were found to undergo successive oxidative demethylations with tropospheric ultraviolet irradiation in the presence of suitable chromophores, such as nitrogen oxides (516). The water-soluble methylated sdicones did not promote diatom (Nap cu/apelliculosd) growth but the demethylated photo products did. The sequence of sod-induced degradation of sdicones to water-soluble species such as (1), followed by light-induced conversion to sdicate, suggests a pathway, conceptually at least, for the mineralization of sdicones. [Pg.61]

Unlike reactive diatomic chalcogen-nitrogen species NE (E = S, Se) (Section 5.2.1), the prototypical chalcogenonitrosyls HNE (E = S, Se) have not been characterized spectroscopically, although HNS has been trapped as a bridging ligand in the complex (HNS)Fc2(CO)6 (Section 7.4). Ab initio molecular orbital calculations at the self-consistent field level, with inclusion of electron correlation, reveal that HNS is ca. 23 kcal mof more stable than the isomer NSH. There is no low-lying barrier that would allow thermal isomerization of HNS to occur in preference to dissociation into H -1- NS. The most common form of HNS is the cyclic tetramer (HNS)4 (Section 6.2.1). [Pg.181]

Equations are balanced by adjusting coefficients in front of formulas, never by changing subscripts within formulas. On paper, the equation discussed above could have been balanced by writing N6 on the right, but that would have been absurd. Elemental nitrogen exists as diatomic molecules, N2 there is no such thing as an N6 molecule. [Pg.61]

What is the molecular weight of each of the substances sulfur (formula, S ), ammonia (formula, NHa), and nitrogen (a diatomic molecule) ... [Pg.34]

The molecular formula of nitrogen is N2 the nitrogen molecule is diatomic. One mole of N2... [Pg.49]

To extract information about xj from NMR data, the transverse relaxation time Tj may be used as well as the longitudinal time T. For gaseous nitrogen it was done first with Ti in [81] and confirmed later [82] when T was measured and used for the same goal. The NMR linewidth of 15N2 is the inverse of T2, and the theory, relating to Ti to x.1, is well known [39, 83]. For the case of diatomic and linear molecules the formula is... [Pg.57]

C02-0081. Air Is mostly diatomic molecules of nitrogen and oxygen, in a molecular ratio of 4 1. Draw a molecular picture of a sample of air containing a total of 10 molecules. [Pg.114]

Nitrogen is a colorless diatomic gas. Phosphorus has several elemental forms, but the most common is a red solid that is used for match tips. Arsenic and antimony are gray solids, and bismuth is a silvery solid. Classify these elements of Group 15 as metals, nonmetals, or metalloids. [Pg.554]

Nitrogen oxide (NO) is an example of heteronuclear diatomic molecules, those composed of different atoms. This interesting molecule has been in the news several times in recent years, because of important discoveries about the role of NO as a biological messenger, as we describe in our introduction to Chapter 21. [Pg.703]


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See also in sourсe #XX -- [ Pg.77 ]

See also in sourсe #XX -- [ Pg.171 ]




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