2- Nitro-1-phenylthio

Analog reagieren (2-Nitro-phenoxy)-, (2-Nitro-phenylthio)-essigsauren bzw. 3-Oxo-3-(2-nitro-phenyl)-propansauren2 ... [Pg.689]

Oxazol 2-(4-Chlor-2-nitro-phenylthio)-5-methoxy- E8a, 950 (CN-CH2-COOR +... [Pg.698]

Pyrrolidin 2-Carboxy-l -(2-nitro-phenylthio)- (Dicyclohexylamin-Salz) XV/1, 204, 218... [Pg.876]

Sulfan Bis-[2-nitro-phenylthio-imino-sulfuranylidenamino]-Ell, 603 (RN = S = NSiRj + SC12)... [Pg.965]

Imidazolidin l-Acetyl-3-tnethyl-2-(nitro-phenylthio-methylen)-E15/3, 2792 (H -+ CO-R)... [Pg.1149]

Butensanre 3-(4-Methoxy-ani-lino)- -ethylester VIII, 627 Chroman 4-(Ethoxycarbonyl-amino)-2-methyl- V/lc, 1106 Cyciobutan 2-(2,5-Dimethoxy-4-methyl-phenyl)-l -hydroximino-E17e, 421 (Oxo - Oxim) Cyclohexan tronj-2-Methoxy-l-(2-nitro-phenylthio)- E21e, 5033 (En -> OR/SAr)... [Pg.1162]

Die Einfiihrung des 4-Nitro-phenylthio-Restes gelingt auch beim Schmelzen von 5-Hydroxy-3-methyl-l-phenyl-lH-pyrazol mit 4-Nitro-thiophenol oder Bis-[4-nitro-phenyl]-disul-fan1541 1542... [Pg.590]

Wahrend 4-(2-Nitro-phenylthiocarbonyl)-3-oxo-tetrahydropyran (konz. Ammoniak/Ethanol) analog zu 2-(2-Carboxymethoxy-ethyl)-l,3-benzothiazol-3-oxid reagiert (68% Schmp. 126-128°), erhalt man aus (l-Methyl-3-(2-nitro-phenylthio)-4-oxo-piperidin (Natronlauge/Te-trahydrofuran) unter zusatzlichcr Spaltung dcr C ,N-Bindung des Piperidin-Ringes 2-Formyl-1,3-benzothiazol (47% Schmp. 72-74°)81. [Pg.873]

Aminomethyl-2-mercapto- 197 2-Amino-4-methyl-5-nitro- 21, 166 2-Amino-5-methyl-4-(3-nitro-phenyl)- 64 2-Amino-4-methyl-5-(4-nitro-phenylthio)- 293... [Pg.1136]

Hydroxy-4-methyl-5-(4-nitro-phenylthio)-aus 2-Hydroxy-4-methyl-l,3-thiazol/4-Nitro-bcnzolsulfenyl-chlorid/Bis-[4-nilro-phenyl]-disulfid 249... [Pg.1148]

Hydroxy-5(3)-melhyl-4-nitro- 560 5-Hydroxy-3-methyl-l-(4-nitro-benzoyl)- 487 3-Hydroxy-5-methyl-4-nitro-l-phenyl- 596 5-IIydroxy-3-methyl-l-(4-nitro-phenyl)- 440 5-Hydroxy-3-methyl-4-(4-nitro-phenylthio)-1-phenyl- 590... [Pg.1171]

Nitro-7-(2-phenyl-ethyl)- 959 2-[3-(4-Nitro-phcnyl)-2-propenoylaraino]- 884 2-[(4-NitrO-phenylthio)-methyl]- 989... [Pg.1192]

Michael addition of nucleophiles to the nitro-(phenylthio)alkene (61) provided, after ozonolysis of the intermediate nitronates, substituted phenylthiol esters (62) with good to excellent diastereoselectivity. They were converted to derivatives (63) of methyl L-alluronate by treatment with methanolic mercury(II) acetate. ... [Pg.141]

Ethylene, /3-(dimethylamino)-nitro-in pyrrole synthesis, 4, 334 Ethylene, dithienyl-in photochromic processes, 1, 387 Ethylene, furyl-2-nitro-dipole moments, 4, 555 Ethylene, l-(3-indolyl)-2-(pyridyl)-photocyclization, 4, 285 Ethylene, l-(2-methyl-3-indolyl)-l,2-diphenyl-synthesis, 4, 232 Ethylene, (phenylthio)-photocyclization thiophenes from, 4, 880 Ethylene carbonate C NMR, 6, 754 microwave spectroscopy, 6, 751 photochemical chlorination, 6, 769 synthesis, 6, 780 Ethylene oxide as pharmaceutical, 1, 157 thiophene synthesis from, 4, 899 Ethylene sulfate — see 2,2-dioxide under 1,3,2-Dioxathiolane... [Pg.623]

Nucleophilic substitution has been used for the preparation of many thiophenes. For instance, 2-phenylthio-3,4-dinitro-5-piperidino-thiophene (155) has been prepared " through stepwise reaction of (150) with different nucleophiles. Nitrothienols and derivatives of them have been obtained from halogenated nitrothiophenes. " Allyl ethers have been prepared by the reaction of 5-chJoro-4-nitro-2-acetylthiophene, 3-nitro-2-chlorothiophene, and 2-nitro-3-bromothio-... [Pg.71]

Stereoselective preparation of CEi-allyl alcohols via radical elimination from ruin -y-phenylthio-fi-nkro alcohols has been reported. The requisiteruin -fi-nitro sulfides are prepared by protonadon of nitronates at low temperanire Isee Chapter 4, and subsequent treatment v/ith Bu-vSnH induces and eliminadon to givelE -alkenes selecdvely IseeEq. 7.112. Unfortunately, it is difficult to get the pure syu-fi-nitro sulfides. Treatment of a rruxnire of syu- and ruin -fi-nitrosulfides v/ith Bu- SnH results in formadon of a rruxnire of (Ey and lZ -alkenes. [Pg.217]

Methoxy- -oxim 379 4-Methoxy-phenyl- 631 -O-methyl-oxim 378 2-Nitro- 311 4-Nitro- 285, 765 -oxim 374, 502. 613 -phenylimin 609 -2-phenyl-propyl-(2)-imin 609 4-Phenylthio- 673 2-Thiocyanat- 635 m,ft),o)-Trifluor- 543... [Pg.884]

Nitro-2,3-dimethyl-butyl-(2)]- 565 4-[2-Nitro-propy]-(2)]- 565 4-(2-Oxo-propyl)- 629 Phenyl- 678 4-Phenylthio- 673 4-(Succinimido-methylamino)- 453 4-Sulfinyl- 680... [Pg.893]

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