Nitric acid triiodide

Dinitrobenzenes Dinitrotoluenes 1,4-Dioxane Esters Ethylamine Ethers Ethylene Nitric acid Nitric acid Silver perchlorate Nitrates Cellulose, oxidizers Oxidizing materials, boron triiodide Aluminum trichloride, carbon tetrachloride, chlorine, nitrogen oxides, tetrafluo-roethylene... 

Nitrogen triiodide a-Nitroguanidine Nitromethane Acids, bromine, chlorine, hydrogen sulfide, ozone Complex salts of mercury and silver Acids, alkylmetal halides, hydroxides, hydrocarbons, organic amines, formaldehyde, nitric acid, perchlorates... 

The addition of water or alkali to the crystals, or to the alcoholic solution, causes blackening, the triiodide and arsenic being formed the decomposition is accelerated by warming. Concentrated sulphuric acid and fuming nitric acid have little action in the cold but, on heating, iodine vapour is expelled, and with the latter acid, iodic and arsenic acids are formed. 

The aliphatic iodine derivatives are usually prepared by reaction of an alcohol with hydroiodic acid or phosphorus triiodide by reaction of iodine, an alcohol, and red phosphorus addition of iodine monochloride, monobromide, or iodine to an olefin replacement reaction by heating the chlorine or bromine compound with an alkali iodide in a suitable solvent and the reaction of triphenyl phosphite with methyl iodide and an alcohol. The aromatic iodine derivatives are prepared by reacting iodine and the aromatic system with oxidizing agents such as nitric acid, fuming sulfuric acid, or mercuric oxide. 

LIQUID AMMONIA (7664-41-7, anhydrous, compressed gas or cryogenic liquid 1336-21-6, solution in water) Difficult to ignite, but can detonate in confined spaces in fire. Reacts violently with strong oxidizers, acids (nitric, hydrochloric, sulfuric, picric, hydro-bromic, hydrochlorous, etc.). Shock-, temperature-, and pressure-sensitive compounds are formed with antimony, chlorine, germanium compounds, halogens, heavy metals, hydrocarbons, mercury oxide, silver compounds (azides, chlorides, nitrates, oxides). Fire and/or explosions may be caused by contact with acetaldehyde, acrolein, aldehydes, alkylene oxides, amides, antimony, boron, boron halides, boron triiodide, bromine, bromine chloride, chloric acid, chlorine, chlorine monoxide, o-chloronitrobenzene, l-chloro-2,4-dinitrobenzene, chlorosilane, chloromelamine, chromium trioxide, chromylchloride, epichlorohydrin, fluorine, hexachloromelamine, hypochlorites (do not mix ammonia with liquid household... 

Iodine content is determined by precipitation as silver iodide from an aqueous solution of methylgermanium triiodide. Germanium is determined by oxidation with mixed nitric and sulfuric acids, followed by ignition to germar-nium(IV) oxide. Anal. Calcd. for CHjGels Ge, 15.49 I, 81.29. Found Ge, 15.7 I, 81.38. 

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