Group 10 nickel

Simultaneous coordination of the type 17 rj-, via the heteroring and saturated substituent, makes the Ni(i7 -cod) complexes 37 and 38 different 

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Properties of copper—nickel alloys are Hsted in Table 14. The alloys in the copper—nickel group have been successfully cast using the centrifugal, investment, permanent, and sand molding methods. The minimum tensile strengths on test bars cast in sand molds are 207—310 MPa (30,000—45,000 psi). 

The univalent anions in this series, unlike those in the nickel group, cannot be prepared satisfactorily by solvent reduction because these anions are themselves reduced slowly by solvents. 

Perchlorate ion complexes, 28 255-299 with cobalt group metals, 28 265-268 coordination types, 28 256-260 with copper group metals, 28 273-283 with early transition metals, 28 260-263 electronic spectra. 28 258-259 ESR spectra, 28 260 infrared and Raman spectra, 28 257-258 with iron group metals, 28 263-265 with lanthanides, 28 260-265, 287-288 magnetic susceptibility, 28 260 molar conductivities, 28 260 with nickel group metals. 28 268-273 X-ray crystal structure analysis, 28 256-257... 

I 18 The Nickel Group (Nickel, Palladium, and Platinum) Tab. 1 Interaction of HCIO4 with nickel... 

This hydride then may add an acetylene molecule to form the vinyl derivative. A carbon monoxide insertion will produce the acrylyl nickel compound which can yield acrylate esters by either of two routes. Direct alcoholysis of the acyl nickel group may take place, as occurs with acylcobalt compounds (42) or, an acyl halide (or other acyl derivative, e.g., acyl alkanoate) may be eliminated. Alcoholysis of the acyl halide would then complete the catalytic cycle (35). 

With most hydrogenation catalysts of the platinum and nickel groups (Sections 4.2.61, p. 459 and 4.2.50, p. 450), a mixture of products is obtained even if an attempt is made to stop the reaction at the half-way stage. An alkene may only be obtained in good yield if particular attention is paid to the selection of a deactivated hydrogenation catalyst. An early, highly effective formulation of a deactivated palladium catalyst is Lindlar s catalyst (Section 4.2.54, p. 453), but palladium-on-barium sulphate in the presence of quinoline, or palladium-on-calcium carbonate, is also recommended. In these cases it is advisable to... 

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