Natural product synthesis Spiculoic Acid

Tadano K-i (2009) Natural product synthesis featuring intramolecular Diels-Alder approaches - Total Syntheses of tubelactomicins and spiculoic acid A. Eur J Oig Chem 4381 394... [Pg.390]

Kirkham, J.E.D., Lee, V., and Baldwin, J.E. (2006) Biomimetic synthesis of marine sponge metabolite spiculoic acid A and establishment of the absolute configuration of the natural product Chem. Commun., 2863-2865. [Pg.371]

Roche ester, (R)-3-hydroxy-2-methylpropionic acid methyl ester (16b), is a chiral building block for the synthesis of vitamins (a-tocopherol), natural products (spiculoic acid A), antibiotics (calcimycin), and fragrance components (muscone) and therefore of high interest for industry. Faber and coworkers employed ERs for the asymmetric synthesis of methyl 2-hydroxymethylacrylate derivatives... [Pg.476]

Mehta, G. and Kundu, U.K. (2005) Toward a total synthesis of the novel polyketide natural product spiculoic acid A. Otg. Lett., 7, 5569-5572. [Pg.1329]

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