N Kinetics

Bikas, G. and Peters, N., Kinetic modelling of M-decane combustion and autoignition. Combust. Flame, 126, 1456, 2001. 

Poth M, DD Focht (1985) N kinetic analysis of N2O production by Nitrosomonas europaea an examination of nitrifier denitrification. Appl Environ Microbiol 49 1134-1141. 

Brovko L.Y., Gandelman O.A., Polenova T.E., Ugarova N.N. Kinetics of bioluminescence in the firefly luciferin-luciferase system. Biochemistry (Russia) 1994 59(2) 195-201. 

Hayes, D., Grieser, F., and Furlong, D.N., Kinetics of hydrogen production form illuminated CdS/Pt/Na2S03 and ZnS/Pt/Na2S03 dispersions, /. Chem. Soc. Faraday Trans., 86, 3637, 1990. 

The species truw5-[0s NN(CH2)40 (tpy)(Cl)2] can be protonated to give the hydrazido(l-) species truw5-[0s N(H)N(CH2)40 (tpy)(Cl)2]. The protonated species undergoes rapid oxidation by benzoquinone, Q, to give tra i-[0s NN(CH2)40 (tpy)(Cl)2] and H2Q. This reaction occurs with a remarkable N— H/N—kinetic isotope effect of 41.4, consistent with a proton-coupled electron transfer mechanism. 

Loun, B. and Hage, D.S., Chiral separation mechanisms in protein-based HPLC columns, n. Kinetic studies of R- and S-warfarin binding to immobilized human serum albumin. Anal. Chem., 68, 1218-1225, 1996. 

The electrostatic interaction between the charge clouds will be large only when there is a spatial overlap of the donor and the acceptor wave functions, i.e. when the two actually collide n kinetic sense. Therefore, it can only be a short range phenomenon. No transfer outside the boundaries of the molecule is expected by this mechanism. The transfer occurs at diffusion-controlled rate. 

Notice that in n-electron multistep electrode reactions, n kinetic parameters, rate coefficients, kh and transfer coefficients or symmetry factors, oth corresponding to each elementary step can be defined. However, these quantities are not directly accessible by experiment. 

Hinshelwood, C. N., Kinetics of Chemical Change in Gaseous Systems, Oxford... 

Prasad, G. N., Kinetic Modeling of Coal Liquefaction Reactions, Ph.D. Thesis, Monash Univ., Australia (1986). 

Martyanov I. N., Kinetics of photocatalytic redox reactions of organic molecules on suspensions of CdS and TiO semiconductors, Ph.D. Thesis. Institute of Catalysis, Novosibirsk (1998) (in Russian). 

Table n. Kinetics for representative reaction pathways for hydrocarbon pyrolysis... 

Al-Ekabi, H. Serpone, N. Kinetic studies in heterogeneous photocatalysis. I. Photo-catalytic degradation of chlorinated phenols in aerated aqueous solutions over Ti02 supported on a glass matrix, J. Phys. Chem. 1988, 92, 5726. 

Minero, C. Aliberti, C. Pelizzetti, E. Terzian, R. Serpone, N. Kinetic studies in heterogeneous photocatalysis. 6. AMI simulated sunlight photodegradation over titania in aqueous media A first case of fluorinated aromatics and identification of intermediates, Langmuir 1991, 7, 928. 

Sattar, A., de Man, J.M., Alexander, J.C. 1977b. Light-induced degradation of vitamins, n. Kinetic studies on ascorbic acid decomposition in solution. Can. Inst. Food Sci. Technol... 

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