Multi-angle laser light scattering detectors

FIGURE 6.4 Comparison of Shodex GPC UT column and conventional-type column. Column Left Shodex GPC UT-806M X 2, 8 mm i.d. X 300 mm X 2. Right Conventional type column X 2, 7.8 mm i.d. X 300 mm x 2. Eluent 0.1% BHT in ODCB. Flow rate 1.0 mL/min. Detector Rl, MALLS (multi-angle laser light scattering detector). Column temp. I45°C. Sample High-density polyethylene. 

FIGURE 6.39 Hydroxyethyl cellulose. Column Left Shodex OHpak SB-806 HQ, 8.0 mm i.d. x 300 mm. Right Shodex Asahipak GF-710 HQ, 7.6 mm i.d. x 300 mm. Eluent 100 mA1 NaNOj. Flow rate 1.0 mL/min. Detector Multi-angle laser light scattering detector. Column temp. 40°C. Sample 0.05%, 200 /iL, Hydroxyethyl cellulose. 

Determined by SEC analysis using a multi-angle laser light scattering detector. 

Fig. 3 GPC setup for functional group profiling. RI refractive index detector Fluorescence fluorescence detector MALLS multi-angle laser light scattering detector...

The CALLS detector is insensitive to low MW and low concentration species. Therefore, the determined by this method may be erroneously high. Another commercially available MW detector is a Multi Angle Laser Light Scattering (MALLS) photometer. It should be noted that a good chromatographic... 

As mentioned in Chap. 1, randomly hyperbranched chains are even more complicated than dendrimers. It has not been completely clear whether they are fractal objects [11, 12] and whether those previously reported M-dependent intrinsic viscosities from an on-line combination of the size exclusion chromatograph (SEC) with viscosity and multi-angle laser light scattering (MALLS) detectors actually captured its structure-property relationship [11, 13]. In the next section, we ll discuss our experimental results in detail. 

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