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Mixed thiolate ligand complexes

TABLE 7. Cyclic voltammetry data(V) of phosphine gold thiolate and mixed donor ligand complexes"... [Pg.328]

Silver(I) trifluoromethanethiolate (AgSCF3) has been used to prepare trifluoromethyl aryl sulfides by reaction with iodide.996 A mixed silver-zinc thiolate complex [Ag4Zn2(SC6H2-Pr -2,4,6)6(OTf)2] has been prepared by reaction of AgOTf with Zn[N(TMS)2]2 in the presence of the thiol.99 Solid-state 109Ag NMR can be a sensitive environment probe for silver thiolates,998 overall for biological thiolates ligands as cysteine,999 or proteins such as metallothionein.1000,1001... [Pg.961]

A number of neutral mixed-ligand oxorhenium(V) complexes containing tridentate [SC2H4YC2Lt4S] (Y = S,0) (95) and monodentate, monoanionic thiolate ligands have been prepared from [ReOCU] and a mixture of the ligands (Scheme The intermediate... [Pg.295]

Rheniumi ) 0x0 bioconjugates have been prepared with chelating NjS donor ligands such as amino/amido/thiolates, mixed-ligand complexes of tridentate ligands with... [Pg.381]

Gold(111) complexes have also been prepared with mixed-donor ligands such as the phosphino thiolates PhP(C6H4SH)2 or P(C6H4SH)3, which give the dinudear... [Pg.47]

When simple nickel(II) salts are treated with thiols, in most cases stable thiolate-bridged polymers are formed. In a number of cases, treating these polymers with either tertiary phosphines or isocyanides gave mononuclear mixed-ligand complexes (equation 204).1951 These mononuclear complexes, due to the presence of terminal thiolates which possess lone pairs, can further react with nickel(II) and give trinuclear complexes (equation 205).1952... [Pg.169]

A great number of studies have addressed the photophysical properties of related Zn(diimine)(SR)2 complexes. Crosby and co-workers (136, 137) investigated many mixed-ligand complexes of Zn(II) and Cd(II) containing diimine ligands and monodentate aromatic thiolate ligands. They note that the rotational... [Pg.355]

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See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.3 , Pg.5 , Pg.6 , Pg.7 ]



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Ligands mixed

Thiolate

Thiolate complexes

Thiolates

Thiolates mixed ligand complexes

Thiolation

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