Mixed-arenethiolatocopper copper halide aggregates

D. Mixed-Organo(arenethiolato)copper and Mixed-Arenethiolatocopper Copper Halide Aggregates... 

It should be noted that, as is the case with the mixed-arenethiolatocopper copper halide aggregates, the metal halide unit forms part of an intimate assembly that produces one well-defined mixed aggregate. 

In the area of mixed-arenethiolatocopper copper halide aggregates, there is still much exploration to be done since so far only two species are known. However, these species have structures that combine several features of both copper arenethiolates and copper halides and may therefore become interesting model compounds in the near future. 

The structures of copper(I) thiolates in which the only other donor functions present are those of the auxiliary ligands (Table III) often resemble structures of those species in which the arenethiolate ligands have a heteroatom containing function that can coordinate intramolecularly to the metal center (Table IV). There are some structurally characterized mixed-organo(arenethiolato)copper(I) and arenethiolatocopper copper halide aggregates in which intramolecular coordination is present. These aggregates are collected in Table V, which allows some direct comparisons to be made between the two types of species. For ease... 

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