Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Methylamine perchlorate

Methylamine dinitramine and dry salts thereof Methylamine nitroform Methylamine perchlorate (dry)... [Pg.475]

AN 44.9, guar flour 0.1 and (methylamine-perchlorate 15, ethanolamine nitrate 43.4, methylamine nitrate 14.4, urea 14-4, AN 12.8%) 30%] 105) F. . Slawinski, USP 3671342 (1972) CA 78, 60376x (1973) (Dynamite compns containing expanded thermoplastic beads. An example is beads 1, 4 1 Nitro-glyeol .Nitroglycerine 37.8, DNT 2.1, Nitro-cotton 0.5, NC 0.3, AN 38.1, sodium nitrate 19.1, wood pulp 3.5 S 1.6 and chalk 1 part such a mixture will explode under 500 feet of water)... [Pg.344]

Methylamine perchlorate, CH3NH3C104 (m.p. 210°C) [28], is a substance that resembles cyclonite and PETN in explosive strength. However, it is more sensitive to impact than these compounds. [Pg.484]

Salts of hydrazine perchlorate and chlorate complexes Nitrosyl perchlorate liydroxylaminc perchlorate Methylamine perchlorate Guanidine perchlorate Nitroguanidinc perchlorate Ruoroammonium perchlorate Nilronium perchlorate Perchloric acid and chlorine oxides Perchloric acid... [Pg.9]

Methylamine. This article supplements the one in Vol 1, A225—7 under Aminomethane and Derivatives CA Registry No 74-89-5 Uses in Explosives. Gaseous methylamine is passed into solid Amm Perchlorate below -6.3° to give useful monoproplnts. A mixt so prepd of 85% Amm Perchlorate and 15% methylamine has an Isp of 230 lbsec/lb at 20atm (Ref 1). [Pg.113]

Methylamine Cupric Perchlorate Complex. (MeNH2)4Cu(Cl04)2, C4H2od2C uN408, mw 386.72, N 14.49%. It is prepd by the interaction of methylamine and Cu(II)perchlorate and is obtd as blue crysts which expld in 30secs at 247°... [Pg.113]

The decomposition of a number of perchlorates containing substituted ammonium groups (various methylamines, guanadine etc.) [935—939] resemble the mechanism proposed for AP decomposition in that proton transfer is identified as the initial step. [Pg.199]

The photooxidation of tertiary methylamines sensitized by electron acceptors such as 9,10-dicyanoanthracene in the presence of lithium perchlorate results in demethylation thus tropinone yields nortropinone257. Photoinduced cyanation of tertiary amines with oxygen, a sensitizer and trimethylsilyl cyanide results in a-cyano nitriles (equation 88)258. [Pg.581]

In a study of detonation of aqueous solutions of perchlorate salts of hydroxy lamine, urea, methylamine and diaminoethane (mono- or di-salts), the former could be detonated in 20-25% solution at 407-587°C. [Pg.324]

Diphenyl-2//-thiopyran 233 is one of the products (12 to 72%) formed by ethanolic methylamine, ethylamine, benzylamine or triethylamine with 2,4-diphenylthiopyrylium perchlorate.273 Trichlorosilane was found to demethylate thiabenzene sulfoxide 234 reductively to mixtures of isomeric thiopyrans 222 and 223.267,274... [Pg.204]

C.J.S.Lundsgaard K.T.Herbst,BritP 168333(1921) USP 1423233(1922) CA 16,344 3399(1922) (Perchlorates of methylamines may be used alone or mixed with other expls for shells, mining expls or for intermediate chges... [Pg.191]

Walter et al (Ref 3) further reports the existence of TeMeAN Perchlorate (see below), which may be useful in pyrots. One method of prepn is by reacting TeMeAN with perchloric acid. The perchlorate is si sol in w. It is considered to be not as sensitive as methylamine nitrate perchlorate. When ignited, the TeMeAN Perchlorate bums with a small bluish-white, sparkling flame... [Pg.571]

Mercury(II) perchlorate. 6 (or 4)dimethyl sulfoxide, 4073 Mercury(II) Af-perchlorylbenzylamide, 3644 Mercury(II) peroxybenzoate, 3630 Mercury(II) picrate, 3427 Mercury(II) sulfide, 4602 Mercury(II) thiocyanate, 0975 Mercury(I) nitrate, 4604 Mercury(I) oxide , 4608 Mercury(I) thionitrosylate, 4605 Mercury, 4595 Mercury nitride, 4610 Mercury peroxide, 4601 (9-MesitylenesuIfonylhydroxylami ne, 3164 Methacryloyl chloride, see 2-Methyl-2-propenoyl chloride, 1453 f Methanamine, see Methylamine, 0491... [Pg.2108]

Tris(2,2-dimethylethyl)triphosphirane, 3570 Tris(dimethylfluorosilylmethyl)borane, 3218 Tris [ 1 -(dimethylsilyl)ethyl]borane, 3578b Tris(ethylthio)cyclopropenium perchlorate, 3173 Tris(hydroxymethyl)methylamine, 1725 f Trisilane, 4574... [Pg.2154]

Avoid skin contact. Flammable by chemical reaction powerful oxidizers. All perchlorates are potentially hazardous when in contact with reducing materials. Moderate explosion hazard when shocked or exposed to heat or by chemical reaction. Perchlorates, when mixed with carbonaceous material, form explosive mixtures. Many perchlorates of nitrogenous bases (e.g., hydroxylamine, urea, methylamine, ethylamine, isopropylamine, 4-ethylpyridine, diaminoethane) and organic perchlorates are explosives. Diazonium perchlorates are very dangerous. All perchlorates are considered to be fire and explosive hazards when associated with carbonaceous materials or finely divided metals. This is also true in the presence of calcium hydride, sulfur,... [Pg.1080]


See other pages where Methylamine perchlorate is mentioned: [Pg.114]    [Pg.329]    [Pg.336]    [Pg.120]    [Pg.484]    [Pg.878]    [Pg.329]    [Pg.115]    [Pg.484]    [Pg.879]    [Pg.682]    [Pg.114]    [Pg.329]    [Pg.336]    [Pg.120]    [Pg.484]    [Pg.878]    [Pg.329]    [Pg.115]    [Pg.484]    [Pg.879]    [Pg.682]    [Pg.258]    [Pg.115]    [Pg.133]    [Pg.92]    [Pg.654]    [Pg.51]    [Pg.537]    [Pg.654]   
See also in sourсe #XX -- [ Pg.484 ]

See also in sourсe #XX -- [ Pg.484 ]




SEARCH



Methylamine

© 2024 chempedia.info