Methyl 4- sulfane

Furan, 2-(methylthio)-, 2-( methylsulfanyl )furan, 2-fury If methyl) sulfane, 2-furyl methyl sulfide, 2-(methylthio)furan [13129-38-9]... [Pg.242]

Furan, 2-[(niethylthio)niethyl]-, 2-[(methylsulfanyUmethyl]furan, furfuryl(methyl)sulfane, furfuryl methyl sulfide [1438-91-1] FEMA 3160... [Pg.245]

Q.12) Ethane, (methylthio)-, ethyl(methyl)sulfane, ethyl methyl sulfide, (methylsulfanyl)ethane, 2-thiabutane 624-89-5 FEMA 3860... [Pg.339]

The synthetic principle of oxidative fluorination is also applicable to pseudohalido derivatives. Difunctional nucleophiles represent an especially important group because of the possible regioselectivity of the monofluoroxenonium salts. In both cyano(methyl)sulfane and dicyanosulfane two different basic centers are possible for the electrophilic attack of the XeF cation. In each case, the corresponding fluorosulfonium salt is formed in HF at 213 K (Figure 1) (18). While S(CN)2F MF6 is observed to disproportionate rapidly in SO2 solution to SF3 MF5 (2) and S(CN)3+MF6" (7P), there is no evidence for such a behavior in the case of CH3S(CN)F+MF6- (M = As, Sb). [Pg.93]

A sequential use of two pericyclic reactions involving sulfur compounds is also implied in a general allylic amination of alkenes with Kresze s reagent, 7V,A -bis(methoxycarbonyl)suIfurdiimide (8). A [2,3] sigmatropy, following an ene reaction of the S-allyl sulfinamidine (9) intermediary formed, affords the diamino sulfane (10), easily converted to the carbamate (11) and then to the amine (12) or (13) [511]. The reactions are featured with 2-methyl-2-butene as the alkene to be functionalized. They are described in Organic Syntheses [512]. [Pg.89]

Sulfane Bis-[4-bromo-N-trifluoro-methyl-anilino]- ElOa. 258 (RN = C = S+ IF,)... [Pg.704]

Sulfane Bis-[tetrafluoro-4-trifluoro-methyl-phenyl]- E10b2. 436 (Educt), 437 (F -> S-Ar)... [Pg.710]

Chlorfenvinphos, chlorpyriphos-methyl, endo-sulfan sulfate, tetradifon, cr-endosulfan, /3-endosulfan, chlorpyriphos-ethyl, carbo-phenothion... [Pg.744]

Analog der im Bd. XII/2, s. 662 erwahnten Reaktion zwischen Thiophosphorsaure-0,0-diestern und (4-Methyl-phenyl)-vinyl-sulfan erfolgt die kationische Addition an N-Vi-nyl-phthalimid in Substanz oder Ethanol bereits bci 20-30° innerhalb 24 Stdn.542 ... [Pg.586]

Spiro(37/-2,l-benzoxathiol-3-one)-l,l -37/-2-methyl-l,3,2-benzodithiazole 3,3-dioxide 179 is readily available from sulfoxide 178 under mild reaction conditions, and optimal 86% yield of spiro-A4-sulfane 179 was achieved after 10-15 min at room temperature. Harsher reaction conditions, that is, 3h at reflux, lead to ring-enlargement product, dibenzodithiazocine 180, in 89% yield (Scheme 48 <1995CC1069>). [Pg.511]

The commercially available materials, HC1, (CH3)3A1, and CF3CC>2H, were purified by trap-to-trap distillation in the vacuum line. S03 was generated as needed by passing the vapors from a sample of Sulfan B over a P205 column. Trimethylgallium was prepared by the reaction of gallium with dimethylmercury at 130° C. Difluoramine was prepared by the thiophenol reduction of tetrafluorohydrazine (3). Methyldifluoramine was obtained by fluorinating sodium N-methyl sulfamate. [Pg.148]

N-Aryl- Ell, 898 (Anilin + Sulfan) N-(4-Methyl-benzolsulfonyl)- Ell, 891 (Chloramin-T + Sulfan)... [Pg.69]

Sulfan Carbamidino-(imino-methylamino-methyl)- (Bis-hydrochlorid) E4, 1017 (H2N-CS-NH-CH3 + NC-NH2)... [Pg.129]

Oxathiolan 2-Ethoxy- E5, 125 Sulfan (Acetoxy-methyl)-ethyl- Ell,... [Pg.228]

Sulfan (Chlor-diethoxyphosphonyl-methyl)-methyl- EI4a/3, 148 (H3C-SO-CH2-P HjC-S-CHCl-P) Sulfenylchlorid... [Pg.324]

Sulfan (1-Acetoxy-l-methyl-ethyl)-isopropyl- Ell, 873 (aus R2SO + Ac20)... [Pg.546]

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