1 -Methyl-5-phenyl-4-trifluormethyl

Methyl-l,3-benzothiazol laBt sich mit Dimethyl-trifluormethyl- und Methyl-phenyl-trifluormethyl-sul-fonium-tetrafluoroborat in 2,3-Dimethyl-l,3-benzothiazolium-tetrafluoroborat iiberfuhren (Acetonitril 0° 8h Ausbeute 96% Schmp. 105c)374. 

C(CII,), -"0 CH3 CF3 cooc2h5 l-tert.-Butyl-4-(4-methyl-phenyl)-5-trifluormethyl-... l-tert.-Butyl-5-ethoxycarbonyl-4-(4-methyl-phenyl)-... 99 87... 

Dipipcridino-phenyl- E2, 482 Di-2-propinyloxy-ethyl- E2, 196 Dipropyl-(4-methoxy-N-lfaethyl-amlino)- E2, 296 Dipropyl-propyloxy- E2, 212 Divinyl-phenyl- E2 874 Ethoxy-ethyl-methoxycarbonylmethyl- E2, 21 Ethoxy-ethyl-phenyl- E2, 23 Ethoxy-hydroxy-methyl- E2, 130, 131 Ethoxy-hydroxy-phenyl- E2, 131, 185, 187, 190, 422 Ethoxy-(2-propinyloxy)-trifluormethyl- E2, 196 Ethyl-ethylthio-(l-methyl-3-oxo-butyl)- E2, 223 Ethyl-methyl-phenyl- -tosylimid E2, 11.3 Ethyl-pbenyl-propyloxy- E2, 281 F.thyl-phenyl-propylthio- E2, 225. Hydroxy-(2-isopropyl-5-methvl-cyclohexvloxv)-methyl- E2, 392... 

Carbamidsanre N-(3-Methyl-phenyl)-N-trifluormethyl- -fluorid E4, 1207 (Ar —NCS + COF2/HgF2)... 

Diaziridin 3-(4-Methyl-phenyl)-3-trifluormethyl- E16c, 682 (Oxim + NH3) lH-(Cyclopenta[d]pyrimidine> ... 

Hydroxylamin N-tm.-Butyl-N-(2-methyl-5-trifluormethyl-phenyl)-E16a. 142 (R-NO + R-M)... 

Bis-[trifluormethyl]-4-(4-methyl-phenyl)-2-trichlormethyl- E14b, 281 (N-Acyl-imin + C13C-CN)... 

Zur Bildung von 4-(4-Methyl-phenyl)-5-trifluormethyl-l,3-thiazol(70%) aus dem 5-Hydroxy-2,5-dihydro-Dcrivat mit Tctraphosphordecasulfid in Benzol s. Lit.1880. 

Amino-2-( 4-methyl-phenyl )-4-trifluormethyl-1,3-thiazol1836 46% Schmp. 135° (Zers.)... 

Methyl-5-phenyl-2-thiono-2,3-dihydro- 361 2-(4-Methyl-phenyl)-4-trifluormethyl-... 

Mit Lithiumalanat werden 5-Ethoxycarbonyl-2,4-difluor-l-(methoxy-methyl)-imidazol zu 4-Fluor-4-hydroxy methyl-1-(methoxy-methyl)-imidazol499 und l-(2,6-Dimethyl-phenyl)-5-fluor-2-phenyl-4-trifluormethyl-imidazol zu l-( 2,6-Dimethyl-pheny )-2-phenyl-4-trifluormethyl-imid-azol927 reduziert. 

O-ethylester-S-propylester- 0-(4-trifluormethyl-thio-phenylester) E2, 713 -lluorid-methylester-(2-phenyl-hydrazid) E2, 683 -fluorid-(2-phenyl-hydrazid) E2, 683 S-(Methoxy-phenylimino-methyl)- -O.O-di-ethylester XII/2, 824 -O-methylester-S-phenylester XII/2, 690 -S-methylester-O-propylester E2, 511 -S-methylester-S-propylester-l-Methoxy-pyridi-nium-Salz E2, 511... 

Diethyl-(4-methoxy-methyl-anilino)- E2, 296 Diethyl-(N-methyl-anilino)- E2, 295, 296 Diethyl-phenoxy- El, 2SI Diethyl-phenyl- -phenylimid XU/1, 177 Difluor-difluormethyl- E2, 836, 854 Difluor-(fluorsulfonyl-methyl)- E2, 857 Difluor-methyl- E2, 836, 854 Difluor-phenyl- E2, 854 Difhior-trifluormethyl- E2, 905 Difluor-triphenyl- E2, 881 Diisopropyloxy-hexyl- El, 135 Diisopropyloxy-methyl- E2, 200, 480 Diisopropyloxy-phenyl- E2. 134, 135, 207 Diisopropyloxy-propyl- E2, 200 Dimcthoxy-methyl- E2, 480 Dimethoxy-phenyl- E2, 204ff, 207, 393, 856, 864 Dimethylamino-diphenyl- E2, 18, 227 Dimethylamino-ethinyl- E2, 230 Dimethylamino-fluor-trifluormethyl- E2, 435 (4-Dimethylamino-phenyl)-diphcnyl- E2, 108 (4-Dimcthylamino-phenyl)-diphcnyl- -(2-nitro-phenylthioimid) E2, 108 Dimethylamino-l-propinyl- E2, 230 (l,l-Dimethyl-butyloxy)-ethyl-methyl- E2, 20, Dimethyl-(diphenylmethylen-amino)- E2, 106 Dimethyl-fluor- E2, 161 Dimethyl-phenyl- E2, 99, 103 Dimethyl-phenyl- -(2-aminocarbonyl-hydrazinocar-bonylimid) E2, 113... 

Pyridinio-methyl- F.2, 605 Tetrafluor-trifluormethyl- E2, 903 (l,l,l-Trimethyl-hydrazinium)-dimethyl- E2, 505 (l,l,l-Trimethyl-hydrazinium)-diphenyl- E2, 505 (1,1,1-Tri me thyl-hydrazinium)-methy l-phenyl-E2, 505... 

Hydro-(4-methyl-phcnyl)-trifluor- E2, 837 Hydro-methyl-trifluor- E2, 836 Flydro-organo-trifluor- E2, 835 Hydro-phenyl-trifluor- E2, 837 Hydro-trifluor-trifluormethyl- E2, 837 Hydroxy-methyl-triphenyl- XII/1, 106 Hydroxy-tetrabenzyl- XII/1, 106 Hydroxy-tetraethyl- XII/1, 106 Isopropyloxy-methyl-triphenyl- E2, 884 Isopropyl-tetrachlor- E2, 430 Methoxy-methyl-triphenyl-... 

---