Methyl complex with

CpFe(CO)2(thf)]+, is generated by protonation of the respective iron-methyl complex with HBF4 in THF solution. Iron-catalyzed reactions of phenyldiazomethane with aldehydes resulted in mixtures of ketones and epoxides [29]. 

Chloro(methyl) complexes, with platinum(II), 8, 450 Chloro methyl diamido complexes, with Ti(IV), 4, 332 Chloropalladium(II) complexes, liquid crystals, 12, 276 //tf/W-Chloro(pentafluorophenyl) complexes, with platinum(II), 8, 485... 

HDS-relevant reactions with metal complexes, 1, 784 metal complex reactions, 1, 785 Dihydro(methyl) complexes, with platinum(IV), 8, 582... 

Octaethylporphyrins, in cobalt(III) complexes, 7, 28 Octahedral hydrotris(pyrazolyl)borate methyl complex, with... 

Tredget, C.S., Lawrence, S.C., Ward, B.D. et al. (2005) A family of scandium and yttrium tris((trimethylsilyl)methyl) complexes with neutral N3 donor Ugands. Organometallics, 24, 3136. 

Stepwise methylation of apical amino substituents in cobalt(III) sarcophaginate make it possible to obtained a tris-N-methylated complex with conformational inversions in the ethylenediamine moieties from mainly a ZeZ -conformation in [Co(diAMsar)] + cation to an 063 conformation in [Co(diMe3AMHsar)]3+ sarcophaginate both in the solid state and in solution [116]. 

Reaction of Methyl Complexes with Propene. Products. 

Subsequent reaction of the methylated complex with an excess of Mel in dichloromethane yields the dimethylated product as in (36). The binuclear system appears to be more reactive than mononuclear analogues such as [Pt(PPh3)3], and this has been ascribed to anchimeric assistance by the second platinum centre (Azam et ai, 1984). A similar reaction has been described for [Pd2(p-dppm)3] (Balch et ai, 1981). 

The diimine of benzaldehyde with // j-(9-l,2-cyclohexanediamine reacts with [PtMe2(//-SMe2)]2 to form a methyl complex with the cyclometallated 6 ,A, iV-tridentate ligand 636. The complex exists as a mixture of racemic stereoisomers. Protonation by [H(OEt)2] in the presence of ethylene produces a cationic complex with 7r-coordinated ethylene 637 (Equation (136)). Complexes with styrene and with propene 638 exhibit high stereoselectivity toward coordination of enantiofaces of the prochiral olefms. ... 

Rare examples of 77 -alkyl clusters are reported. The 77 -methyl complexes with /X3-chalcogenido-bridged triiron cores, [MeFe3(GO)9(/X3-E)] 66 (E = Se, Te), are synthesized by methylation of the corresponding dianion with... 

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