Skeletal metals

Pr )2(PPh3)7](PFg)2-3249 and [Au, i(PPlioIV1 e)i(l]3, 3250 The structure of the mixed-ligands clusters corresponds to a C3v metal skeletal framework and the homoleptic to a centered bicapped square antiprism (Figure 32). Other stoichiometries are known as, for example, [AunCl2(PPh3)8]Cl.3251... 

Promoter species have been mentioned previously. These are additional metals or organic compounds present in either the original alloy or in the lixiviant. They are more than just a second catalytic metal, although bi-metal skeletal catalysts are possible. Promoter species increase the activity of the... 

Figure 1. The metal skeletal frameworks of (a) [H3Rhi3 CO)24], (b) [Rhi4(CO)25], and (c) [OsioC(CO)24], showing their similarities to a fragment of a HCP, BCC and CCP lattice, respectively.

Positional or permutational isomerism occurs in compounds which have the same metal skeletal framework but differ in the occupation of the vertices of the poly-hedron, " for example, complexes C and D (Fig. 2). ... 

Bifunctional (metallic and acidic functions) catalysts are applied to a variety of oil-refining and petrochemical processes. For example, paraffin hydroisomerization involves n-paraffins dehydrogenation to a-olefins over metal, skeletal isomerization of n-olefins to isoolefins over acidic sites, followed by hydrogenation of isoolefins to isoparaffins over metal. Zeohte-supposted noble metal catalysts are often used for these types of reactions, which... 

The catalytic hydrogenation of ethylene occurs on various metal catalysts, such as nickel, including active or skeletal forms produced by dissolving out... 

PHOSPHAZENES CONTAINING SKELETAL CARBON, SULFUR, AND METAL ATOMS... 

The polyions postulated in solution all have known structural analogues in crystalline borate salts. Investigations of the Raman (66) and B nmr (67) spectra of borate solutions have confirmed the presence of three of these species the triborate (3), B202(0H) 4, tetraborate (4), [B40 (0H) 4], and pentaborate (5) B O (OH) 4, polyanions. Skeletal stmctures were assigned based on coincidences between the solution spectra and those soHd borates for which definitive stmctural data are available (52). These same ions have been postulated to be present in alkah metal borate glasses as well. 

An extremely wide variety of catalysts, Lewis acids, Brmnsted acids, metal oxides, molecular sieves, dispersed sodium and potassium, and light, are effective (Table 5). Generally, acidic catalysts are required for skeletal isomerization and reaction is accompanied by polymerization, cracking, and hydrogen transfer, typical of carbenium ion iatermediates. Double-bond shift is accompHshed with high selectivity by the basic and metallic catalysts. 

Locations. Galvanic corrosion of any type is most severe in immediate proximity to the junction of the coupled metals. Galvanic corrosion of weld metals is frequently microstructurally localized. The less-noble weld material will corrode away, leaving behind the skeletal remnants of the more-noble metal (Figs. 15.1 and 15.2). 

Metal Catalyzed Skeletal Reactions of Hydrocarbons J. R. Anderson... 

Sandwich complexes nickel. 5, 35 Sapphyrins, 2, 888 demetallation, 2, 891 metallation, 2, 891 reactions, 2, 891 synthesis, 2, 889 Sarcoplasmic reticulum calcium/magnesium ATPase, 6, 566 skeletal muscle... 

Site symmetry symbols, I, 128 Six-coordinate compounds stereochemistry, 1, 49-69 Six-membered rings metal complexes, 2, 79 Skeletal muscle sarcoplasmic reticulum calcium pump, 6, 565 Slags... 

Other heterocyclosiloxanes in which one or more of the skeletal silicon atoms have been replaced by an atom of another main group element or transition metal are well-known and have been extensively studied [136],... 

Because the complexes listed in Tables 1-8 are all prepared with metal halides and carborane anions, only one example for each type of metallocarborane (number of B atoms) is given in the following representative equations for clarity, the skeletal framework in the equations have numbered positions and H atoms are omitted ... 

The octahedron is classified into the c/o o-structure by Wade [3,4]. Closo-structures with n skeletal atoms are stable when they have 4n-i- 2 valence electrons. Wade s rules predict that the 26 (= 4 x 6 + 2) valence electrons could stabilize the regular octahedrons since n is 6 for the octahedron. This prediction is contained in our 6N + 14 (N= 2) valence electron rule. Our rule also predicts the stability of octahedral metal clusters with the other numbers (14 and 20) of valence electrons. 

A major feature of the polyphosphazene skeleton is its ability to resist fire and combustion due to the inorganic elements constitutive of its structure [44,387, 388,459,460]. Moreover, the action of skeletal nitrogen and phosphorus atoms can be enhanced by inserting additional inorganic elements (F, Cl, Br, J, B, metals, etc.) in the substituent groups [459,460]. 

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