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Metal-containing compounds, Rhodium periodate

This preparation is an illustration of the hydroformylation of olefins (oxo synthesis). The reaction occurs in the presence of soluble catalytic complexes containing metals of Group VIII of the periodic system. Although the metal originally used by Roelen and still largely used in the industry for the production of aliphatic aldehydes and alcohols is cobalt, the most active and selective catalysts are rhodium-containing compounds. The catalytic activity of the other Group VIII metals is in... [Pg.76]

Organometaiiic chemistry started some forty years ago and developed rapidly, particularly that part involving transition metals. This can be illustrated by the facts that, in the period 1981-1992, not less than 1319 stable organometaiiic compounds containing rhodium, a relatively rare member of the platinum group, were described (Sharp, 1995), or that stable complexes containing diazenido ligands with at least 19 transition metals are known (Sutton, 1993). On the other hand, no aryldiazenido complex of copper has been described, in spite of the fact that such coordination compounds may be formed in the Sandmeyer, Pschorr, and Meerwein reactions. The latter have been known, in part, for more than a century We are aware, of course, that the search for the structure of catalysts is methodically very different from that for stable compounds. This is likely to be the reason that in the majority of review papers either structures of stable compounds or catalysts are discussed but correlations between these areas of interest are not. ... [Pg.456]


See other pages where Metal-containing compounds, Rhodium periodate is mentioned: [Pg.13]    [Pg.253]    [Pg.556]    [Pg.224]    [Pg.1038]    [Pg.4083]    [Pg.91]    [Pg.88]    [Pg.4082]    [Pg.676]    [Pg.668]    [Pg.1038]    [Pg.4492]    [Pg.719]    [Pg.11]    [Pg.656]    [Pg.750]    [Pg.725]    [Pg.714]    [Pg.748]    [Pg.668]   
See also in sourсe #XX -- [ Pg.105 , Pg.268 ]




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