Antiferromagnetic metals

Ce3Cu3Sb4 was found to be a semiconducting ferromagnet with ferromagnetic transition temperature, Tm = 10 T while GdTTitSh4 was reported to be a metallic antiferromagnet with 7n = 12K(Patil et al., 1996). 

Intense efforts in the last decade have exhaustively mapped the electronic and superconducting properties of intercalated alkali fullerides and the occurrence of the metal-antiferromagnetic insulator transition as a function of inter -fullerene separation, orientational order/disorder, valence state, orbital degeneracy, low-symmetry distortions and metal-C60 interactions [6-12]. 

First-principles calculations have been performed to study the electronic band structure and the magnetic properties for thiazole complex, Fe(thiazole)2Cl2. From the total and the partial density of states and the atomic spin magnetic moments, it was found that Fe(thiazole)2Cl2 is a metallic antiferromagnet and has a half-metallic (HM) ferromagnetic metastable state <2006PLE245>. 

Half-Metallic Antiferromagnetic (HMAFM) Double Perovskites... 

The hexaborides for which the oxidation state of the metal is 2 -f- are CaB, SrBg, BaB5, EuB, YbB. They are diamagnetic except EuB, which is ferromagnetic (Tc = 12.5 K) . The other rare-earth hexaborides are characterized by the 3-1-oxidation state, except for SmB, in which samarium is in a mixed valence state. They exhibit antiferromagnetic order at low T except LaB, YB and SmB . ... 

In an earlier work, we have proposed a theoretical procedure for the spectroscopy of antiferromagnetically (AF) coupled transition-metal dimers and have successfully applied this approach to the electronic absorption spectrum of model 2-Fe ferredoxin. In this work we apply this same procedure to the [Fe2in - 82) P o - CeH48)2)2 complex in order to better understand the electronic structure of this compound. As in our previous work" we base our analysis on the Intermediate Neglect of the Differential Overlap model parameterized for spectroscopy (INDO/S), utilizing a procedure outlined in detail in Reference 4. 

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