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Mercury drop electrode

Mercury electrodes (a) hanging mercury drop electrode (b) dropping mercury electrode (c) static mercury drop electrode. [Pg.509]

A form of voltammetry using a dropping mercury electrode or a static mercury drop electrode. [Pg.515]

Potential-excitation signal and voltammogram for anodic stripping voltammetry at a hanging mercury drop electrode. [Pg.518]

Faraday s law (p. 496) galvanostat (p. 464) glass electrode (p. 477) hanging mercury drop electrode (p. 509) hydrodynamic voltammetry (p. 513) indicator electrode (p. 462) ionophore (p. 482) ion-selective electrode (p. 475) liquid-based ion-selective electrode (p. 482) liquid junction potential (p. 470) mass transport (p. 511) mediator (p. 500) membrane potential (p. 475) migration (p. 512) nonfaradaic current (p. 512)... [Pg.532]

Electrodes. The Hanging Mercury Drop Electrode is traditionally associated with the technique of stripping voltammetry and its capabilities were investigated by Kemula and Kublik.51 In view of the importance of drop size it is essential to be able to set up exactly reproducible drops, and this can be done as explained in Section 16.8 for the S.M.D.E. [Pg.623]

Voltaic cells 64. 504 Voltammetry 7, 591 anodic stripping, 621 concentration step, 621 mercury drop electrode, 623 mercury film electrode, 623 peak breadth, 622 peak current, 622 peak potential, 622 purity of reagents, 624 voltammogram, 622 D. of lead in tap water, 625 Volume distribution coefficient 196 Volume of 1 g of water at various temperatures, (T) 87... [Pg.877]

DME = dropping mercury electrode HMDE = hanging mercury drop electrode MFE = mercury film... [Pg.2]

FIGURE 1-13 Double-layer capacitance of a mercury drop electrode in NaF solutions of different concentrations. (Reproduced with permission from reference 5.)... [Pg.22]

The mercury film electrode has a higher surface-to-volume ratio than the hanging mercury drop electrode and consequently offers a more efficient preconcentration and higher sensitivity (equations 3-22 through 3-25). hi addition, the total exhaustion of thin mercury films results in sharper peaks and hence unproved peak resolution in multicomponent analysis (Figure 3-14). [Pg.79]

There are several types of mercury electrodes. Of these, the dropping mercury electrode (DME), the hanging mercury drop electrode (HMDE), and mercury film electrode (MFE) are the most frequently used. [Pg.108]

FIGURE 4-7 The static mercury drop electrode and its cell stand. [Pg.109]

Electrochemical analytical techniques are a class of titration methods which in turn can be subdivided into potentiometric titrations using ion-selective electrodes and polarographic methods. Polarographic methods are based on the suppression of the overpotential associated with oxygen or other species in the polarographic cell caused by surfactants or on the effect of surfactants on the capacitance of the electrode. One example of this latter case is the method based on the interference of anionic surfactants with cationic surfactants, or vice versa, on the capacitance of a mercury drop electrode. This interference can be used in the one-phase titration of sulfates without indicator to determine the endpoint... [Pg.281]

The properties of anodic layers of HgS formed on mercury in sulfide solutions have been investigated in comparison with anodic sulfide layers of cadmium and bismuth. Also, the electrochemistry of mercury electrodes in aqueous selenite solutions has been studied (see Sect. 3.2.1). The problem with the presence of several cathodic stripping peaks for HgSe in acidic Se(IV) solutions has been addressed using various voltammetric techniques at a hanging-mercury-drop electrode [119]. [Pg.106]

Fig, 16. Anodic stripping voltammogram for at the hanging mercury drop electrode. (Reprinted with permission from W. R. Heineman, in Water Quality Measurement The Modem Analytical Techniques , (H. B. Mark, Jr. and J. S. Mattson, eds.) Marcel Dekker New York, 1981)... [Pg.39]

HMDE Hanging mercury dropping electrode mass spectrometry... [Pg.755]

QTA Quartz tube atomiser SDME Static mercury drop electrode... [Pg.759]

See other pages where Mercury drop electrode is mentioned: [Pg.1933]    [Pg.509]    [Pg.509]    [Pg.509]    [Pg.518]    [Pg.532]    [Pg.533]    [Pg.540]    [Pg.540]    [Pg.773]    [Pg.776]    [Pg.779]    [Pg.49]    [Pg.346]    [Pg.609]    [Pg.621]    [Pg.865]    [Pg.870]    [Pg.37]    [Pg.89]    [Pg.109]    [Pg.207]    [Pg.221]    [Pg.566]    [Pg.72]    [Pg.40]    [Pg.669]    [Pg.671]    [Pg.760]   
See also in sourсe #XX -- [ Pg.180 ]



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