Mercapto complexes

The mercapto complex Rh(SH)(CO)(PPh3)2 can be made by an unusual route [60] involving COS, where an intermediate with CS bound COS has been suggested. 

Quantification was performed by external scanning of the column and analysis of the activity profile of the retained Tc compounds (mercapto complexes, diphospho-nates, etc.), using a modified thin-layer scanner. 

Previous studies of mono- and bis-CO substitution in mercapto-complexes [Fe2(CO)6(/w-SR)2] and isostructural nitrogen-bridged derivatives by Group Vb bases ERs provide evidence for an S n2 or /a bimolecular mechanism (see Vol. 4 p. 281) ... 

Triazine-3,5-dione, 6-mercapto-metal complexes, 3, 456 oxidation, 3, 411... 

In contrast to heterogeneous metal catalysts, the chlororhodium complex is not sensitive to sulfur poisoning,thus allowing the saturation of double bonds in the presence of mercapto functions. 

Propane-1,2-diol, 3-mercapto-metal complexes, 2,804 Propan-l-ol, 2-amino-2-methyl-copper(II) complexes, 2,795 Propan-l-ol, 2,3-dimercapto-chelating agent heavy metal poisoning, 6,767 Propan-l-ol, 3-(methylamino)-copper(II) complexes, 2,795 Propan-2-ol... 

Quinoline, 8-mercapto-2-methyl-metal complexes, 2, 800 Quinoline, 2-methyl-8-(methylthio)-metal complexes, 2,801 Quinoline, 8-methylthio-metal complexes, 2, 801 Quinoline-2-carboxylic-acid, 8-hydroxy-methyl ester... 

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