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Maxwells Demon

Since no Maxwell Demon is at hand to officiate in these unions, each pair of units participating in the formation of a cross-linkage will be selected at random it is required merely that the partners be in suitable proximity at the instant of formation of the linkage. From a chemical point of view, cross-linkages are scattered throughout the bulk of the... [Pg.458]

Dual Phase Continuity. Dual phase continuity has been shown to be important in numerous polymer blends and IPN s, to achieve special properties. Dual phase continuity is defined as a region of space where two phases maintain some degree of continuity. An example of dual phase continuity is an air filter and the air that flows through it. A Maxwell demon could traverse all space within the air filter phase, as well as within the air phase. [Pg.238]

A major interest to sequential IPN s relates to dual phase continuity, defined as a region of space where each of two phases maintain some degree of connectivity. An example is an air filter with the air flowing through it. A Maxwell demon can transverse all space within both the filter phase and the air phase, both phases being continuous. [Pg.275]

Beside static mixers, there are practically no alternatives to the "ubiquitous" stirred tank, if one excepts loop reactors (167) and the somewhat special back-flow mixer (168). Imagining entirely new principles for mixing reactants is a challenge for future researchers. First estimations show that an "informed" mixing system, working as a Maxwell demon would be much more effective than our present devices (169). [Pg.185]

In cell and molecular biology where mechanisms of enzyme action are not understood and attributed to some kind of Maxwell demon, all is specificity, and the lipids of membranes serve to do no more than act as a passive matrix for proteins and as a protection for the procreation of a uni-dimensional, machine like and stolidly boring DNA. There is more to it than that. [Pg.392]

Let us now employ Maxwell demons to put both chains under tension with force of magnitude / applied at both ends of each chain, stretching them out as sketched in Fig. 3.8. As in Section 2.6.1, we subdivide each chain into tension blobs of size containing g monomers each, such that on length scales smaller than these tension blobs the chain statistics are unperturbed,----------------------------------------------------... [Pg.105]

It is sometimes supposed that to maintain a constant S, im monomers reenter the system at the same rate that W-mers leave. The imax-mcrs are said to be broken up by Maxwell demons. [Pg.508]

Fig. 4. Ouster growth and shrinkage processes including a Maxwell demon to break up large clusters of size g into clusters of size 1. Fig. 4. Ouster growth and shrinkage processes including a Maxwell demon to break up large clusters of size g into clusters of size 1.
Fig. 18. Reformulation of Fig. 17. The old double index (i,y) is replaced by a single index i (i +1)/2 + j. Only clusters with i j can exist. A Maxwell demon is introduced to break up clusters with g vacancies. Fig. 18. Reformulation of Fig. 17. The old double index (i,y) is replaced by a single index i (i +1)/2 + j. Only clusters with i j can exist. A Maxwell demon is introduced to break up clusters with g vacancies.
Figure 8.10. Schematic representation of a concentration profile as found by a Maxwell demon traveling through a midrange composition, semicompatible IPN. Figure 8.10. Schematic representation of a concentration profile as found by a Maxwell demon traveling through a midrange composition, semicompatible IPN.
Barring minor impurities, an ordinary rubber band consists of only one molecule. This fits both portions of the definition of a molecule. (1) A Maxwell demon can traverse the entire system by stepping on adjacent covalent bonds, and (2) the entire rubber band is the smallest entity having the properties of rubber bands. Breaking the rubber band creates a new material, for then it cannot bind things together in the ordinary manner. [Pg.2]

This oscillatory behavior is counterintuitive and apparently nonphysical it seems to violate the laws of thermodynamics. In fact, it does. One reason is that our assumption of equal transit times for all molecules across the membrane requires a Maxwell demon to help molecules avoid the collisions that produce a distribution of transit times. [Pg.222]

Reversible computation has a very important consequence until 1961 scientists believed that any computational action would result in an energy cost. But in 1961 Rolth Landauer showed [17] that what do cost energy is erasure. In other words, if no bit is lost during the computation, it can be made at energy-free cost This discovery lead to the solution of a century-old problem in thermodynamics the Maxwell demon problem. [Pg.20]

Figure 1.7 The Maxwell demon is capable of measuring the energy of each molecule in the gas, and let the slower (light ones) pass to the left, and the faster (dark ones) to the right, through the opening aperture he controls. After a while the left side of the container is at a temperature lower than the right side. Has the demon cheated the second law of thermodynamics ... Figure 1.7 The Maxwell demon is capable of measuring the energy of each molecule in the gas, and let the slower (light ones) pass to the left, and the faster (dark ones) to the right, through the opening aperture he controls. After a while the left side of the container is at a temperature lower than the right side. Has the demon cheated the second law of thermodynamics ...
The weak van der Waals potential between He atoms and the bosonic nature of He also are basic for understanding why He is the only bulk superfluid below Tc = 2.18 if at 0.05 bar. The rare isotope He, a fermion, on the other hand, only becomes superfluid at a three orders of magnitude lower temperature. There are many well known macroscopic manifestations of superfluidity such as (i) flow without resistance (ii) a vanishing viscosity (iii) the ability to creep out of vessels against the forces of gravity (iv) the fountain effect which is driven by a type of Maxwell demon which separates the superfluid from the normal fluid components and (v) an enormous thermal conductivity which is 30 times greater than that of copper. Table 7.1 compares some properties of liquid argon (also a cry-omatrix) with those of helium in the normal and in the superfluid state. [Pg.347]

There are several the stages in a product life cycle and the way in which it interacts with the environment. From the extraction stage, the materials are processed, manufactured, utilized and wasted, being, in a greater or lesser fashion, raised, manufactured and recycled. Such an interaction with the environment is inherent to the production processes due to the very fact that they require inputs fi om the surroundings (energy, ores, fuel, etc.) as well as, like the Maxwell demon, their very presence interferes with the surroundings (7). [Pg.295]


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