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Maximal intensity

For a redox center with an EPR signal in its oxidized state (e.g., a Cu"/Cu couple or an Fein/Fen couple), the maximal intensity would be on the right side of the graph and would fit the equation... [Pg.217]

In 1965, a gas-phase chemiluminescent reaction between ozone and ethylene was reported by Nederbragt et and the sensitivity of this technique was later improved by Warren and Babcock.The reaction between ozone and ethylene yields chemiluminescent emission in the 300- to 600-nm region, with maximal intensity at 435 nm. The intensity of this emission is directly proportional to the ozone concentration. [Pg.267]

Bipolar disease, or recurrent unipolar disease may be manic-depressive illness. This disease can manifest as typical bipolar disease, with alternating depressive and manic episodes, or as recurrent depression (or more rarely recurrent mania). The age of onset and frequency of recurrence may be highly variable, with at best a single episode, where the disease may be suspected from family history. The intensity of individual episodes may vary from the maximal intensities of depression, also called melancholia, or mania justifying rapid hospitalisation to barely pathological mood swings, where it is an alternation and... [Pg.681]

Fig. 7.10. Maximal intensity of the ROE as a function of (A) magnetic field for x, = 10 ns and (B) tr at a field of 800 MHz, for two hydrogen nuclei at 1.8 A distance. Curves (a), (b) and (c) refer to a field-independent R pM (Eq. (3.21)) of 0, 50 and 200 s-1, respectively. For R pM 0, the fast motion limit is the same as that of transient ROE the slow motion limit is positive and equal to 0.675. Fig. 7.10. Maximal intensity of the ROE as a function of (A) magnetic field for x, = 10 ns and (B) tr at a field of 800 MHz, for two hydrogen nuclei at 1.8 A distance. Curves (a), (b) and (c) refer to a field-independent R pM (Eq. (3.21)) of 0, 50 and 200 s-1, respectively. For R pM 0, the fast motion limit is the same as that of transient ROE the slow motion limit is positive and equal to 0.675.
Fig. 8.10. Computer-simulated NOESY cross peaks between signals with different T2 values. Conditions p[ — p =40 s 1 p[ - 50 s-1 p( = 200 s I o/j = 5 s l. (A) f[" = t2m = 0.01 s (B) t["ax = T , r2max = T2J (C) t["ax = T, r2max = T. Note that the upper left cross peak has maximal intensity in case (B), the lower right cross peak has maximal intensity in case (C), whereas in case A the two intensities are equal and intermediate between the larger and the smaller of cases (B) and (C). For simplicity, fra = T[ = T( has been taken. A cos2 weighting function has been applied. Fig. 8.10. Computer-simulated NOESY cross peaks between signals with different T2 values. Conditions p[ — p =40 s 1 p[ - 50 s-1 p( = 200 s I o/j = 5 s l. (A) f[" = t2m = 0.01 s (B) t["ax = T , r2max = T2J (C) t["ax = T, r2max = T. Note that the upper left cross peak has maximal intensity in case (B), the lower right cross peak has maximal intensity in case (C), whereas in case A the two intensities are equal and intermediate between the larger and the smaller of cases (B) and (C). For simplicity, fra = T[ = T( has been taken. A cos2 weighting function has been applied.
Ju. For T2 <3C 1/(27//), maximal intensity is obtained for fj = 27 ./ and tf = 2T(. Of course, at these short time values, the sine build up of the interaction is small. Weighting functions of sin, sin2 or matched-filter-type are used to maximize the signal-to-noise ratio. In any case, since the T2 values in paramagnetic compounds are small, the cross peak intensity is drastically reduced. [Pg.284]

Fig. 5.6 Example of different steps of reduction in 2-D transforms. Original image is a contour plot of a part of a 2-D NMR spectrum. The contours represent the intensity-levels at 5, 10 and 30% (full line) and at -5, -10 and -30% (dashed line) of the maximal intensity value. The reproductions with 1/2 and 1/4 of the coefficients are shown separately for FFT and FHT. Fig. 5.6 Example of different steps of reduction in 2-D transforms. Original image is a contour plot of a part of a 2-D NMR spectrum. The contours represent the intensity-levels at 5, 10 and 30% (full line) and at -5, -10 and -30% (dashed line) of the maximal intensity value. The reproductions with 1/2 and 1/4 of the coefficients are shown separately for FFT and FHT.
In this wide-beam simulation, the initial condition is a Gaussian pulse with a phase perturbation. The waist of the initially collimated Gaussian was chosen to be 5 mm, the pulse duration is 500 fs, A = 248 nm, and the maximal intensity is 2 x 1014Wm-2. The total pulse energy is approximately 9mJ. A random phase perturbation is imposed on the pulse to initiate the transverse break-up of the pulse into multiple filaments (see Fig 13.3). We adjusted the amplitude of the perturbation such that it results in the filamentation onset after a few meters of propagation. [Pg.271]

Figure 15.6 Determination of the maximal intensity variation at pH 3 and 7 using the highest values of A/and of [TIMS],... Figure 15.6 Determination of the maximal intensity variation at pH 3 and 7 using the highest values of A/and of [TIMS],...
This disordering must occur preferentially within planes perpendicular to the Si-backbone axis, as evidenced by the maximized intensity of this halo at the meridional region. [Pg.357]

IR spectra of H-boralites show four hydroxyl bands at 3450, 3680, 3720 and 3740 cm. These bands were assigned [7,11] to Si—OH—O, B—OH, Si—OH -B, and terminal Si—OH respectively. In the case of H-ZSM-5, two bands were observed 3610 (Si—OH— Al) and 3740 cm (terminal Si—OH). The sorption of pyridine resulted in a reaction of Si—OH - B and Si—OH—A1 groups and the formation of PyH ions. The maximal intensity of PyH band was used to calculate the content of Brdnsted acid sites in the boralites and zeolites studied. These concentrations are presented in Table 2. After the neutralization of all Bronsted acid sites pyridine was desorbed. This was accompanied by the diminishing of PyH and reappearance of acidic hydroxyl bands (3720 cm in the case of boralites or 3610 cm in the case of H-ZSM-5). The intensities of both PylT and OH bands are presented in Figure 1. [Pg.241]

It may... be that emotional impulse as evoked by relevant stimuli potentially always is of maximal intensity, regardless of realistic or moralistic considerations this impulse is toned down by inhibition, as a permanent stabilizing counterforce governed by reality and morality. Sham rage, Mark and Ervin s observations on unrestrained anger, enhancement of startle response... [Pg.296]

The half width, co, introduced by Scherrer, corresponding to the angular range in which the intensity is larger or equal to half the maximal intensity (now designed as the FWHM, full width at half maximum). A size parameter is defined from co by ... [Pg.142]

Another approach is to intentionally select a very small coupling optimization such that integer multiples of that coupling will be in phase and read out at the end of the experiment with maximal intensity. The author (GEM) and a co-worker reported this approach using a 1.75 Hz optimization in the acquisition of proton double quantum coherence of strychnine (1) many years ago with some degree of success. [Pg.4]

When an antigen to which a normal patient has been exposed previously is injected into the skin, the area of the injection becomes infiltrated with lymphocytes within a few hours. In the next stage, additional lymphocytes and phagocytes (e.g., macrophages, neutrophils) infiltrate. The maximal intensity of the inflammatory reaction occurs by 24 to 72 hours. This reaction is often referred to as type FVhypersensitivity (i.e., cell-mediated see Chap. 86). In type I hypersensitivity, a positive skin reaction is evident usually within 15 minutes and always within 24 hours. Type I hypersensitivity involves the release of histamine from basophils and mast cells when antigen binds to the IgE on the surfaces of these cells. [Pg.1575]

Fig. 6. Activation of caspases detected by the fluorochrome-labeled caspase (FLICA) inhibitors assay. FiL-60 cells were untreated (A), treated in culture with camptothecin to induce apoptosis (B) (ref. 26). The cells were then electrostatically attached to microscope slides, incubated with staining solution of FAM-VAD-FMK as described in the protocol, and their green fluorescence (integrated value and pixel of maximal intensity) measured by LSC. Note the appearance of apoptotic cell subpopulation characterized by the increased green fluorescence (above the marked threshold level of the maximal pixel) reflecting activation of caspases that bind FAM-VAD-FMK. Fig. 6. Activation of caspases detected by the fluorochrome-labeled caspase (FLICA) inhibitors assay. FiL-60 cells were untreated (A), treated in culture with camptothecin to induce apoptosis (B) (ref. 26). The cells were then electrostatically attached to microscope slides, incubated with staining solution of FAM-VAD-FMK as described in the protocol, and their green fluorescence (integrated value and pixel of maximal intensity) measured by LSC. Note the appearance of apoptotic cell subpopulation characterized by the increased green fluorescence (above the marked threshold level of the maximal pixel) reflecting activation of caspases that bind FAM-VAD-FMK.
Peroxide-induced luminescence was also recorded from luminous tissues of 30 different sharks, grouped by 10 cm categories, via a luminometer Berthold FB12. Light response was standardized using the maximal intensity of light in megaquanta per second per square centimetre for each luminous zone (Z,max in Mq.s .cm"2). [Pg.16]

Quantitative criteria of expression efficiency of bioluminescence were copy number of lux-operon (level of a replication) in a cell, duration of the latent period of induction of bioluminescence (level of a transcription), the maximal intensity of luminescence (level of a translation). The following quantitative criteria and coefficients are used fi - number of copies of /wx-operons in a cell (for natural marine bacteria - 1 operon/chromosome, for transgenic luminous bacteria the parameter varies depending on strain). Number of copies of plasmid was determined on electrophoregrams with program Scion Image f2 = 1/t - coefficient (s 1), which reflects influence of the latent period in dynamics of bioluminescence on expression... [Pg.101]


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