Manganese organometallics

Carbonylation Processes by Homogeneous Catalysis Coordination Chemistry History Coordination Numbers Geometries Iron Organometallic Chemistry Manganese Organometallic Chemistry Nickel Organometallic Chemistry Rhodium Organometallic Chemistry. 

Phosphine complexes with alkyl ligands are discussed in the chapter Manganese Organometallic Chemistry. 

Softer nucleophiles N, for example, H or PBub, add directly (reversibly in the latter case) to the exo face of the arene to give the [Re(j7 -C6R6N-6-exo)(CO)3] (142) complexes without any participation of the metal center. Attempted extension to Re complexes of the well-established methodology for double functionalization of arenes earlier developed for the Mn analogs on the basis of [Mn(j -dienyl)(CO)2(NO)]+ (see Manganese Organometallic Chemistry) is thwarted by the limitations foimd in the preparation of the cations [Re()]5 -dienyl)(CO)2 (NO)]+. 

Carbonyl Complexes of the Transition Metals Electronic Structure of Organometallic Compounds Flydride Complexes of the Transition Metals Ligand Field Theory Spectra Manganese Organometallic Chemistry Photochemistry of Transition Metal Complexes Rhenium Organometallic Chemistry Ruthenium Organometallic Chemistry. 

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