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Manganese isocyanides

Cyclic Voltammethic Data on Manganese(I) Isocyanide Species - ... [Pg.27]

The reaction of Mn(CO)jBr and methyl isocyanide was also carried out (Table V) the products are analogous to those obtained from phenyl isocyanide and the manganese complex. [Pg.55]

Mixed methyl isocyanide carbonyl manganese(I) cations [Mn(CO)5 j(Ljf]-PFj (L = CNCHj) were prepared by the standard method 154). The... [Pg.56]

C2H,N, Pyridine, 3,5-dimethyl-palladium complex, 26 210 CbHsNO, Benzoyl isocyanide chromium com-C HbO, Ethanone, 1-phenyl-manganese complex, 26 156-158 CBH, 02, Methyl benzoate chromium complex, 26 32 C H i, o-Xylylene magnesium complex, 26 147 ChH P, Phosphine, dimethylphenyl-iron complex, 26 61 ruthenium complex, 26 273 ChH12, 1,5-Cyclooctadiene iridium complex, 26 122 ruthenium complexes, 26 69-72, 253-256 ChH OjPS, 2-Butenedioic acid, 2-(dimethylphosphinothioyl)-dimethyl ester, manganese complex, 26 163... [Pg.415]

There are no routes yet to homoleptic metal isocyanide anions. If one considers the interesting products obtained from methyl iodide additions to molybdenum (43) and manganese (44) carbonyl isonitrile anions, negatively charged isocyanide complexes should have some interesting chemistry. Also, now that a simple route to [CpFe(CNR)2]2 complexes has been devised (45), the synthesis of the anion [CpFe(CNR)2] could provide a route to a range of products including heterometal-metal bonded systems. [Pg.212]

Unipositive manganese appears in the ion [Mn(CN)g] , obtained when yellow solutions of [Mn (CN)g] ions are reduced with aluminium powder and alkali. When Mnig is treated with alkyl isocyanides, compounds are formed containing the [Mn(RNC)g]+ ion (Sacco and Naldini, 1956). [Pg.478]

Isocyanides CNR can act as terminal ligands or as a group to insert into an M—R bond, M—C(NR)R. The reaction of the benzyl manganese(I) derivatives Mn(CH2Ar)(CO) with aliphatic isocyanides ... [Pg.624]

KETONES 1,3-Benzodithiolylium perchlorate. Benzyl(chloro)bis(triphenyl-phosphine)palladium. Chlorobis-(cyclopentadienyl)hydridozirconium. Iron carbonyl. Manganese(ll) iodide. Silver acetate. Thionyl chloride. Tosylmethyl isocyanide. Tri-p-carbonylhexacarbonyldiiron. [Pg.583]

Other Manganese(i) Complexes.—Treatment of Mn(N03)2,6H20 with high-boiling isocyanides RNC (R = p-anisyl, p-tolyl, or benzyl) in methanol under vacuum yields [Mn(CNR)g](N03)2 and/or [Mn(CNR)g](N03). The bivalent products can be converted into the univalent state by treatment with aceto-nitrile. ... [Pg.191]

OgMnPCgiHig, Manganese, octacarbonyl-1 ic C,2ic C-/i-[carbonyl-2icC 1 xO-6-(diphenylphosphino-2icP)-o-phenylene-2icC licC ]di-, 26 158 04MoN2Ci4Hig, Molybdenum, bis(tert-butyl isocyanide)tetracarbonyl-, cis-, 28 143... [Pg.431]

C4 2H30IaMnNg, Hexakis(phenyl isocyanide)manganese(I) triiodide, 46B,... [Pg.409]

See other pages where Manganese isocyanides is mentioned: [Pg.56]    [Pg.56]    [Pg.151]    [Pg.54]    [Pg.59]    [Pg.435]    [Pg.37]    [Pg.968]    [Pg.215]    [Pg.216]    [Pg.230]    [Pg.255]    [Pg.80]    [Pg.138]    [Pg.135]    [Pg.217]    [Pg.34]    [Pg.229]    [Pg.51]    [Pg.210]    [Pg.476]    [Pg.1069]    [Pg.136]    [Pg.414]    [Pg.623]    [Pg.624]    [Pg.634]    [Pg.381]    [Pg.401]    [Pg.199]   


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