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Manganese imines

An alternative preparation of aziridines reacts an alkene with iodine and chloramine-T (see p. 1056) generating the corresponding A-tosyl aziridine. Bromamine-T (TsNBr Na ) has been used in a similar manner." Diazoalkanes react with imines to give aziridines." Another useful reagent is NsN=IPh, which reacts with alkenes in the presence of rhodium compounds or Cu(OTf)2 to give N—Ns aziridines. Manganese salen catalysts have also been used with this reagent. ... [Pg.1058]

Kumar, R., Sithambaram, S. and Suib,S.L. (2009) Cyclohexane oxidation catalyzed by manganese oxide octahedral molecular sieves - effect of acidity of the catalyst. Journal of Catalysis, 262,304—313. Sithambaram, S., Kumar, R., Son, Y. and Suib, S.L. (2008) Tandem catalysis direct catalytic synthesis of imines from alcohols using manganese octahedral molecular sieves. Journal of Catalysis, 253, 269-277. [Pg.239]

A number of pendant arm ligand derivatives based on hexamine macrocyclic backbones have been reported." One such species was formed by the [2 -f 2] Schiff base condensation between 3,3-iminobis(propylamine) and diformyl-p-cresol followed by sodium borohydride reduction of the four imine functions so generated. Potentiometric studies indicate that a range of both mononuclear and dinuclear species are formed in solution with manganese(II) incorporating various both protonated and nonprotonated forms of the ligand. [Pg.75]

Manganese(II) has been commonly employed as a templating metal ion for the synthesis of a wide range of other mixed donor (oxygen/nitrogen) Schiff base macrocycles (and/or their imine-reduced derivatives). [Pg.78]

Electrophilic aromatic substitution of 708 with the iron-coordinated cation 602 afforded the iron-complex 714 quantitatively. The iron-mediated quinone imine cyclization of complex 714, by sequential application of two, differently activated, manganese dioxide reagents, provided the iron-coordinated 4b,8a-dihydrocarbazole-3-one 716. Demetalation of the iron complex 716 with concomitant... [Pg.233]

Electrophilic substitution at the arylamine 709 using the complex salt 602, provided the iron complex 725 quantitatively. Sequential, highly chemoselective oxidation of the iron complex 725 with two, differently activated, manganese dioxide reagents provided the tricarbonyliron-complexed 4b,8a-dihydrocarbazol-3-one (727) via the non-cyclized quinone imine 726. Demetalation of the tricarbonyliron-complexed 4b,8a-dihydrocarbazol-3-one (727), followed by selective O-methylation, provided hyellazole (245) (599,600) (Scheme 5.70). [Pg.236]

Electrophilic aromatic substitution of the arylamine 780a using the iron-complex salt 602 afforded the iron-complex 785. Oxidative cyclization of complex 785 in toluene at room temperature with very active manganese dioxide afforded carbazomycin A (260) in 25% yield, along with the tricarbonyliron-complexed 4b,8a-dihydro-3H-carbazol-3-one (786) (17% yield). The quinone imine 786 was also converted to carbazomycin A (260) by a sequence of demetalation and O-methylation (Scheme 5.86). The synthesis via the iron-mediated arylamine cyclization provides carbazomycin A (260) in two steps and 21% overall yield based on 602 (607-609) (Scheme 5.86). [Pg.245]

The total synthesis of carbazomycin D (263) was completed using the quinone imine cyclization route as described for the total synthesis of carbazomycin A (261) (see Scheme 5.86). Electrophilic substitution of the arylamine 780a by reaction with the complex salt 779 provided the iron complex 800. Using different grades of manganese dioxide, the oxidative cyclization of complex 800 was achieved in a two-step sequence to afford the tricarbonyliron complexes 801 (38%) and 802 (4%). By a subsequent proton-catalyzed isomerization, the 8-methoxy isomer 802 could be quantitatively transformed to the 6-methoxy isomer 801 due to the regio-directing effect of the 2-methoxy substituent of the intermediate cyclohexadienyl cation. Demetalation of complex 801 with trimethylamine N-oxide, followed by O-methylation of the intermediate 3-hydroxycarbazole derivative, provided carbazomycin D (263) (five steps and 23% overall yield based on 779) (611) (Scheme 5.91). [Pg.250]

Grigg and co-workers (383) found that chiral cobalt and manganese complexes are capable of inducing enantioselectivity in 1,3-dipolar cycloadditions of azomethine ylides derived from arylidene imines of glycine (Scheme 12.91). This work was published in 1991 and is the first example of a metal-catalyzed asymmetric 1,3-dipolar cycloaddition. The reaction of the azomethine yhde 284a with methyl acrylate 285 required a stoichiometric amount of cobalt and 2 equiv of the chiral ephedrine ligand. Up to 96% ee was obtained for the 1,3-dipolar cycloaddition product 286a. [Pg.885]

Arylazoarylimines (527), with a methyl or ethyl group ortho to the imine function (prepared by oxidation with manganese dioxide of arylaminohydrazones from anilines (525) and chlorohydrazones... [Pg.653]

One of the earliest Schiff base macrocycles to exhibit a haemocyanine-like structure was the copper(II) perchlorate complex of 5.5 which binds readily to azide or hydroxide.8 The azide complex exhibits two square pyramidal copper binding domains with the basal plane occupied by one pyridyl nitrogen atom and two imine functionalities as well as a terminal azide ligand. The apices of the two pyramidal coordination polyhedra are linked by a single bridging azide anion. Continuing the biomimetic theme, manganese (II) cascade complexes of the unsymmetrical 5.6 have... [Pg.323]

Whilst the chiral manganese complexes can epoxidize alkenes with high enantioselectivity (> 90% e.e.), they are not particularly stable. This instability is probably due to the easily oxidizable imine and phenoxide ligands on the complex. Attempts are currently being made to immobilize Schiff-bases in order to increase their stability in a similar manner to the metalloporphyrins discussed earlier. [Pg.51]

Another aspect of the mode of action of ellipticine and its derivatives that has been intensely scrutinized in recent years is the chemistry of ellipticine quinone imines 6 and 256. The oxidation product of 9-hydroxyellipticine (3), formed by horseradish peroxidase-hydrogen peroxide or chemical (e.g., manganese dioxide) oxidation of 3, undergoes a rich array of chemical reactions. Meunier et al. [Pg.312]


See other pages where Manganese imines is mentioned: [Pg.603]    [Pg.86]    [Pg.254]    [Pg.507]    [Pg.1122]    [Pg.250]    [Pg.436]    [Pg.436]    [Pg.64]    [Pg.66]    [Pg.128]    [Pg.129]    [Pg.87]    [Pg.88]    [Pg.212]    [Pg.37]    [Pg.536]    [Pg.64]    [Pg.536]    [Pg.254]    [Pg.117]    [Pg.48]    [Pg.868]    [Pg.200]    [Pg.790]    [Pg.1246]    [Pg.507]    [Pg.2524]    [Pg.123]    [Pg.280]    [Pg.1001]    [Pg.51]    [Pg.250]   
See also in sourсe #XX -- [ Pg.347 , Pg.348 , Pg.349 , Pg.350 , Pg.351 , Pg.352 , Pg.353 , Pg.354 ]




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