Manganese complexes photochemistry

K. FI. van Dijik, J. van der Haar, D. J. Stufkens, and A. Oskam, Metal to hgand charge-transfer photochemistry of metal-metal-honded complexes.7. Photochemistry of (CO)4CoM(CO)3(bpy) (M=Mn, Re bpy=2, 2 -Bipyridine) Photochatalyic disproportionation of the manganese complex in the presence ofPR3, Inorg. Chem. 28 75 (1989). 

Harriman, A. Photochemistry of Manganese Complexes, Coord. Chem. Revs. 1979,28,147. Jamieson, M. A. Seipone, N. Hoffinan, M. Z. Advances in the Photochemistry and Photophysics of Chromium(ni) Polypyridyl Complexes in Fluid Solution, Coord. Chem. Revs. 1981,39,121. Kirk, A. D. Chromium(ni) Photochemistry and Photophysics, Coord. Chem. Revs. 1981,39,225-293. Kutal, C. Spectroscopic and Photochemical Properties of d Metal Complexes, Coord. Chem. Revs. 1990,99,213. 

Wrighton MS, Ginley DS. Photochemistry of metal-metal bonded complexes. II. The photochemistry of rhenium and manganese carbonyl complexes containing a metal-metal bond. J Am Chem Soc 1975 97(8) 2065-2072. 

Carbonyl Complexes of the Transition Metals Electronic Sfructme of Organometalhc Compounds Hydride Complexes of the Transition Metals Ligand Field Theory Spectra Manganese Organometalhc Chemistry Photochemistry of Transition Metal Complexes Rhenium Organometalhc Chemistry Rutheiuum Organometalhc Chemistry. 

Reviews have appeared of the photophysics of molybdenum complexes, primary and secondary processes in organometallic chemistry, flash photolysis of Pe(CO)5 and Cr(CO)g, dinuclear manganese carbonyl compounds, the photochemistry of metal complexes isolated in low temperature matrices, cluster complexes, diene complexes, photoproduction of coordinativeiy unsaturated species containing rhodium or iridium, and redox chemiluminescence of organometallic compounds.Synthetic and metal organic photochemistry in industry has also been reviewed. 

The formation of both Mn(CO)s and the CO-loss product, Mn2(CO)9, from UV photolysis of Mn2(CO)io has been investigated by ultrafast IR spectroscopy.Density functional calculations have been performed on the ground and excited states of MnCl(CO)5, as an aid to understanding the photochemistry of MX(C0)5 complexes (M = Mn, Re X = Cl, Br, I). The lowest energy excitations are to the Mn-Cl a orbital, and these states are dissociative for both axial and equatorial CO loss, but not for Mn-Cl bond homolysis. The photochemistry of manganese carbonyl complexes (58, R = Me, benzyl R = /-Pr, p-tolyl) depends critically on the R group.CO is released with R = Me, but with R = benzyl there is efficient homolysis of the Mn-R bond. ... 

Other light-absorbing compounds that may be present in marine aerosol particles and contribute to photochemistry include transition metals, nitrate anions, amines, polyaromatic hydrocarbons, and other organic molecules. Transition metal complexes (including iron, copper, manganese, nickel) are... 

Photochemistry of Manganese (II) 2-Ethylhexanoate films. An amorphous film of manganese (II) 2-ethylhexanoate was prepared by spin coating a solution of the complex in CH2CI2 onto a silicon substrate. The photolysis of the complex was... 

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