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Main phase transition, spectrum

Figure 4 Spectrum of 6-d DPPC Belov (34°C) and Above (49°C) the Main Phase Transition. Figure 4 Spectrum of 6-d DPPC Belov (34°C) and Above (49°C) the Main Phase Transition.
Figure 5 Gel Phase CD- Rocking Mode Spectrum of 4-d, DPPE. The molecule has lts main phase transition at 6A°C. The residual gel phase disorder is substantial. Figure 5 Gel Phase CD- Rocking Mode Spectrum of 4-d, DPPE. The molecule has lts main phase transition at 6A°C. The residual gel phase disorder is substantial.
Membrane proteins should be placed in a bilayer which is as similar as possible to its native environment. There is a diverse spectrum of phosphlipid bilayers available - differing mainly in the charges of their polar head groups, lengths and saturation of their acyl chains. If lipids play key roles in the proteins function, different combinations of Hpads will probably better represent the in vivo conditions. It should always be kept in mind that in order to simulate the membrane in a liquid-crystalline state the temperature of the simulation needs to be above the melting temperature of the chosen lipids (phase-transition temperature). [Pg.382]

Here a third selection rule applies for linear molecules, transitions corresponding to vibrations along the main axis are allowed if Aj = 1. The A/=0 transition is only allowed for vibrations perpendicular to the main axis. Note that because of this selection rule the purely vibrational transition (called Q branch) appears in the gas phase spectrum of C(X but is absent in that of CO. In both cases, two branches of rotational side bands appear (called P and R branch) (see Fig. 8.3 for gas phase CO). [Pg.222]

The successful prediction of superconductivity in the high pressure Si phases added much credibility to the total energy approach generally. It can be argued that Si is the best understood superconductor since the existence of the phases, their structure and lattice parameters, electronic structure, phonon spectrum, electron-phonon couplings, and superconducting transition temperatures were all predicted from first principles with the atomic number and atomic mass as the main input parameters. [Pg.261]

Experimentally, the spectrum of Ni(CO)4 has been measured in solution [76], in matrix [61] and, more recently, in gas-phase [65]. The solution spectrum exhibits a main peak at 6.0 eV, with two shoulders at 5.5 and 5.2 eV. Only the 5.2 eV band could be detected in the matrix isolation spectrum, with a new shoulder appearing at 4.5 eV. Finally, in the gas-phase spectrum a main peak at 6.0 eV and two shoulders at 5.4 and 4.6 eV could be discerned. Being a d10 system, d—>d ligand field (LF) transitions are absent in the spectrum. Since Ni(CO)4 has Ta symmetry, only excitations from the Ai... [Pg.68]


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See also in sourсe #XX -- [ Pg.4 , Pg.6 ]

See also in sourсe #XX -- [ Pg.4 , Pg.6 ]




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Main phase transition

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