Magnetic resonance method

H. Strehlow, Rapid Reactions in Solution, VCH, Weinheim, Germany, 1992. Recent review of perturbation kinetics and magnetic resonance methods. 

Spectrometric Analysis. Remarkable developments ia mass spectrometry (ms) and nuclear magnetic resonance methods (nmr), eg, secondary ion mass spectrometry (sims), plasma desorption (pd), thermospray (tsp), two or three dimensional nmr, high resolution nmr of soHds, give useful stmcture analysis information (131). Because nmr analysis of or N-labeled amino acids enables determiaation of amino acids without isolation from organic samples, and without destroyiag the sample, amino acid metaboHsm can be dynamically analy2ed (132). Proteia metaboHsm and biosynthesis of many important metaboUtes have been studied by this method. Preparative methods for labeled compounds have been reviewed (133). 

Magnetic resonance methods in the study of the electronic structure of transition metal complexes. 

Magnetic resonance methods include the applications of NMR and EPR spectroscopies. The occurrence of exchange reactions leads to line broadening. The analysis of the line shapes allows the rate constant to be determined. 

Solid state materials have been studied by nuclear magnetic resonance methods over 30 years. In 1953 Wilson and Pake ) carried out a line shape analysis of a partially crystalline polymer. They noted a spectrum consisting of superimposed broad and narrow lines which they ascribed to rigid crystalline and amorphous material respectively. More recently several books and large articles have reviewed the tremendous developments in this field, particularly including those of McBrierty and Douglas 2) and the Faraday Symposium (1978)3) —on which this introduction is largely based. 

P. Blunder, B. Bliimich, R. E. Botto, E. Fuku-shima (eds.) 1998, Spatially Resolved Magnetic Resonance Methods, Materials, Medicine, Biology, Rheology, Geology, Ecology, Hardware, VCH, Weinheim, 774 pp. Collected lectures from an MR imaging conference, various fields, also contains chemical engineering and transport. 

T. Zavada, R. Kimmich 1998, (The anomalous adsorbate dynamics at surfaces in porous media studied by nuclear magnetic resonance methods. The orientational structure and Levy walks), J. Chem. Phys. 109, 6929. 

Nuclear Magnetic Resonance Method for Relative Configuration Determination... 

Most of the attempted asymmetric reductions have used sodium borohydride in conjunction with quaternary ammonium catalysts. Recently, the solution structures of ion pairs formed by quaternary ammonium ions derived from quinine with borohydride ion have been characterized by nuclear magnetic resonance methods in CDC13.1741... 

Optical and nuclear magnetic resonance methods apphcable to moderately strong electrolytes have been made increasingly precise (14). By these methods, it has proved feasible to determine concentrations of the undissociated species and hence of the dissociation constants. Thus, for HNO3 in aqueous solution (14) at 25°C, K is 24. However, in dehning this equilibrium constant, we have changed the standard state for aqueous nitric acid, and the activity of the undissociated species is given by the equation... 

J.J. Delpuech, M.A. Hamza, G. Serratrice, Determination of oxygen by a nuclear magnetic-resonance method, J. Magn. Reson. 36 (1979) 173-179. 

A nuclear magnetic resonance method for chlorpromazine has been reported [178]. For tablets, capsules, and bulk chemical, the sample is shaken with CHCI3 containing cyclohexane or piperanol as an internal standard. For injectable solutions, tetramethylammonium bromide was used as the internal standard. The NMR spectrum was recorded between 0 and 7.0 ppm, and the drug resonance at 2.7 ppm (relative to TMS) measured. The signals for the respective internal standards were at 1.5, 6.0, and 3.3 ppm. 

Li, C.-Y. et al., Efficient IH nuclear magnetic resonance method for improved quality control analyses of ginkgo constituents, J. Agric. Food Chem., 52, 3721, 2004. 

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