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Magnetic field effects principles

This adiabatic principle was one of the corner-stones of the old quantum theory. It allowed one to find the quantum conditions when an adiabatic change was imposed on a system. It was used successfully to account for the Stark and Zeeman effects in the spectrum of atomic hydrogen, resulting from the application of an electric and magnetic field respectively (Schwartzchild [1916] Epstein [1916]). [Pg.20]

In this short review, a brief overview of the underlying principles of TDDFT has been presented. The formal aspects for TDDFT in the presence of scalar potentials with periodic time dependence as well as TD electric and magnetic fields with arbitrary time dependence are discussed. This formalism is suitable for treatment of interaction with radiation in atomic and molecular systems. The Kohn-Sham-like TD equations are derived, and it is shown that the basic picture of the original Kohn-Sham theory in terms of a fictitious system of noninteracting particles is retained and a suitable expression for the effective potential is derived. [Pg.80]

In 1925, Wolfgang Pauli gave chemists what they wanted from the physicists a physical principle underlying electron-pair valency. Pauli built on the fact that in addition to the continuous, line, and band spectra, there is a fine structure of doublets, triplets, and multiple lines, some of which are split in a magnetic field (Zeeman effect). [Pg.248]

For a description of the electron-counting procedure as applied to metal clusters, see Ref 37.) The paramagnetism of the nickel cluster, in principle, could be detected directly by neutron diffraction with a polarized beam and an external magnetic field. However, such measurements were not undertaken, and the effects of paramagnetism on the observed diffraction intensities, that are small in the present experiment, were ignored. [Pg.78]

Nan and Weng (1999) have developed a Green function method to determine self-consistently the effective magnetostrictive properties of composites. The authors claim that their method, in principle, can be used to study the effects of material constants and microstructure, such as anisotropy, particle shape and orientation relative to the applied magnetic field. [Pg.173]

Figure 14.13—Zeeman effect correction. Instrument showing the principle used for correction of absorbance by the Zeeman effect. Two solutions are applicable I) magnetic field, B, switched alternately on and off and a fixed polariser 2) fixed magnetic field, B, and a rotating polariser. Figure 14.13—Zeeman effect correction. Instrument showing the principle used for correction of absorbance by the Zeeman effect. Two solutions are applicable I) magnetic field, B, switched alternately on and off and a fixed polariser 2) fixed magnetic field, B, and a rotating polariser.
The principle of nonperfect synchronization recent developments, 44, 223 Products of organic reactions, magnetic field and magnetic isotope effects on, 30, 1 Protic and dipolar aprotic solvents, rates of bimolecular substitution reactions in, 5,173 Protolytic processes in H20—D20 mixtures, 7, 259... [Pg.408]


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