Magnesium Diazide

Magnesium Diazide (formerly called Magne-stum Azoimide or Magnesium Trinitride, Mg(Nj)2, mw 108.37, N 77.56% wh ppt sol in w, insoi in eth or tetrahydrofuran. The prepn of Mg diazide was attempted in 1898 by dissolving the merstl in di 1 HNj, but the product decompd on evapg the soln and was not isolated (Ref 1). Turrentine (Ref 2) studied the.electrochem corrosion of Mg in Na azide soln and obtd a wh flocculent ppt, probably basic magnesium azide, Mg(OH)N3, but he did not identify the product. Browne... 

After pumping the solvents and excess acid off at room temperature, the white product was considered a solvent-free magnesium diazide [113], but in the absence of analytical data and in light of general experience with azidation of magnesium organyls, its purity is unconfirmed. 

Bis(cyclopentadienyl)bis(pentafluorophenyl)zirconium, 3824 Bis(cyclopentadienyldinitrosylchromium), 3269 Bis(cyclopentadienyl)hexafluoro-2-butynechromium, 3629 Bis(cyclopentadienyl)lead, 3288 Bis(cyclopentadienyl)magnesium, 3271 Bis(cyclopentadienyl)manganese, 3272 Bis(cyclopentadienyl)niobium tetrahydroborate, 3318 Bis(cyclopentadienyl)pentafluorophenylzirconium hydroxide, 3696 Bis(cyclopentadienyl)phenylvanadium, 3698 Bis(cyclopentadienyl)titanium selenate, 3287 Bis(cyclopentadienyl)tungsten diazide oxide, 3279 Bis(cyclopentadienyl)vanadium diazide, 3280 Bis(cyclopentadienyl)zirconium, 3290 Bis(l,2-diaminoethane)diaquacobalt(III) perchlorate, 1787 Bis(l,2-diaminoethane)dichlorocobalt(III) chlorate, 1780 Bis(l,2-diaminoethane)dichlorocobalt(III) perchlorate, 1781 c/i-Bisf 1,2-diaminoethane)dinitrocobalt(III) iodate, 1782 Bis(l,2-diaminoethane)dinitrocobalt(III) perchlorate, 1778 Bis(l,2-diaminoethane)hydroxooxorhenium(V) perchlorate, 1785 Bis(l, 2-diaminopropane)-ds-dichlorochromium(III) perchlorate, 2609 1,10-Bis(diazonio)decaboran(8)ate, 0197... 

DIAZIDE (333-41-5) A weak base. Hydrolyzes slowly in water and dilute acid. With excess water, this compound produces diethylthiophosphoric acid and 2-isopropyl-4-methyl-6-pyrimidol. With insufficient water, this compound produces highly toxic tetraethyl monoth-iopyrophosphate. Incompatible with antimony(V) pentafluoride, diacetate, magnesium, silver nitrate. Reacts with strong acids, alkalis, copper-containing compounds, oxidizers. 

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