Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Lotka-Volterra

In 1914, F. W. Lanchester introduced a set of coupled ordinary differential equations-now commonly called the Lanchester Equationsl (LEs)-as models of attrition in modern warfare. Similar ideas were proposed around that time by [chaseSS] and [osip95]. These equations are formally equivalent to the Lotka-Volterra equations used for modeling the dynamics of interacting predator-prey populations [hof98]. The LEs have since served as the fundamental mathematical models upon which most modern theories of combat attrition are based, and are to this day embedded in many state-of-the-art military models of combat. [Taylor] provides a thorough mathematical discussion. [Pg.592]

Autocatalysis can cause sustained oscillations in batch systems. This idea originally met with skepticism. Some chemists believed that sustained oscillations would violate the second law of thermodynamics, but this is not true. Oscillating batch systems certainly exist, although they must have some external energy source or else the oscillations will eventually subside. An important example of an oscillating system is the circadian rhythm in animals. A simple model of a chemical oscillator, called the Lotka-Volterra reaction, has the assumed mechanism ... [Pg.57]

FIGURE 2.6 Population dynamics predicted by the Lotka-Volterra model for an initial population of 100 rabbits and 10 lynx. [Pg.57]

The Lotka-Volterra reaction described in Section 2.5.4 has three initial conditions—one each for grass, rabbits, and lynx—all of which must be positive. There are three rate constants assuming the supply of grass is not depleted. Use dimensionless variables to reduce the number of independent parameters to four. Pick values for these that lead to a sustained oscillation. Then, vary the parameter governing the grass supply and determine how this affects the period and amplitude of the solution. [Pg.74]

Figure 3-34. Lotka-Volterra s predator and prey kinetics . Figure 3-34. Lotka-Volterra s predator and prey kinetics .
Figure 3-35. The concentration of wolves plotted versus the concentration of sheep in the Lotka-Volterra predator-prey kinetics. Figure 3-35. The concentration of wolves plotted versus the concentration of sheep in the Lotka-Volterra predator-prey kinetics.
From a mathematical point of view, the onset of sustained oscillations generally corresponds to the passage through a Hopf bifurcation point [19] For a critical value of a control parameter, the steady state becomes unstable as a focus. Before the bifurcation point, the system displays damped oscillations and eventually reaches the steady state, which is a stable focus. Beyond the bifurcation point, a stable solution arises in the form of a small-amplitude limit cycle surrounding the unstable steady state [15, 17]. By reason of their stability or regularity, most biological rhythms correspond to oscillations of the limit cycle type rather than to Lotka-Volterra oscillations. Such is the case for the periodic phenomena in biochemical and cellular systems discussed in this chapter. The phase plane analysis of two-variable models indicates that the oscillatory dynamics of neurons also corresponds to the evolution toward a limit cycle [20]. A similar evolution is predicted [21] by models for predator-prey interactions in ecology. [Pg.255]

Chemistry Basic Elements Lotka-volterra Mechanism ... [Pg.298]

Lastly, non-elementary several-stage reactions are considered in Chapters 8 and 9. We start with the Lotka and Lotka-Volterra reactions as simple model systems. An existence of the undamped density oscillations is established here. The complementary reactions treated in Chapter 9 are catalytic surface oxidation of CO and NH3 formation. These reactions also reveal undamped concentration oscillations and kinetic phase transitions. Their adequate treatment need a generalization of the fluctuation-controlled theory for the discrete (lattice) systems in order to take correctly into account the geometry of both lattice and absorbed molecules. As another illustration of the formalism developed by the authors, the kinetics of reactions upon disorded surfaces is considered. [Pg.51]

The better known Lotka-Volterra model [18, 19] unlike (2.1.21) is based on two autocatalytic stages... [Pg.61]

This type of a pattern of singular points is called a centre - Fig. 2.3. A centre arises in a conservative system indeed, eliminating time from (2.1.28), (2.1.29), one arrives at an equation on the phase plane with separable variables which can be easily integrated. The relevant phase trajectories are closed the model describes the undamped concentration oscillations. Every trajectory has its own period T > 2-k/ujq defined by the initial conditions. It means that the Lotka-Volterra model is able to describe the continuous frequency spectrum oj < u>o, corresponding to the infinite number of periodical trajectories. Unlike the Lotka model (2.1.21), this model is not rough since... [Pg.62]

Fig. 2.3. A centre. Three solutions of the Lotka-Volterra equations (2.1.28)-(2.1.29) are presented the distinctive parameter a//3 = 1. The starting point of each trajectory is shown by... Fig. 2.3. A centre. Three solutions of the Lotka-Volterra equations (2.1.28)-(2.1.29) are presented the distinctive parameter a//3 = 1. The starting point of each trajectory is shown by...
More interesting aspects of stochastic problems are observed when passing to systems with unstable stationary points. Since we restrict ourselves to mono- and bimolecular reactions with a maximum of two intermediate products (freedom degrees), s — 2, only the Lotka-Volterra model by reasons discussed in Section 2.1.1 can serve as the analog of unstable systems. [Pg.99]

As was noted in Section 2.1.1, the concentration oscillations observed in the Lotka-Volterra model based on kinetic equations (2.1.28), (2.1.29) (or (2.2.59), (2.2.60)) are formally undamped. Perturbation of the model parameters, in particular constant k, leads to transitions between different orbits. However, the stability of solutions requires special analysis. Assume that in a given model relation between averages and fluctuations is very simple, e.g., (5NASNB) = f((NA), (A b)), where / is an arbitrary function. Therefore k in (2.2.67) is also a function of the mean values NA(t) and NB(t). Models of this kind are well developed in population dynamics in biophysics [70], Since non-linearity of kinetic equations is no longer quadratic, limitations of the Hanusse theorem [23] are lifted. Depending on the actual expression for / both stable and unstable stationary points could be obtained. Unstable stationary points are associated with such solutions as the limiting cycle in particular, solutions which are interpreted in biophysics as catastrophes (population death). Unlike phenomenological models treated in biophysics [70], in the Lotka-Volterra stochastic model the relation between fluctuations and mean values could be indeed calculated rather than postulated. [Pg.101]

Fig. 2.13. The random trajectory in the stochastic Lotka-Volterra model, equation (2.2.64). Parameters are a/k = /3/k = 20, the initial values NA = NB = 20. When the trajectory coincides with the NB axis, prey animals A are dying out first and predators second. Fig. 2.13. The random trajectory in the stochastic Lotka-Volterra model, equation (2.2.64). Parameters are a/k = /3/k = 20, the initial values NA = NB = 20. When the trajectory coincides with the NB axis, prey animals A are dying out first and predators second.
Analysis of equations for second momenta like (SNA5NB), (5Na)2) and (5NB)2) shows that all their solutions are time-dependent. In the Lotka-Volterra model second momenta are oscillating with frequencies larger than that of macroscopic motion without fluctuations (2.2.59), (2.2.60). Oscillations of k produce respectively noise in (2.2.68), (2.2.69). Fluctuations in the Lotka-Volterra model are anomalous second momenta are not expressed through mean values. Since this situation reminds the turbulence in hydrodynamics, the fluctuation regime in this model is called also generalized turbulence [68]. The above noted increase in fluctuations makes doubtful the standard procedure of the cut off of a set of equations for random values momenta. [Pg.103]

Systems Under Birth and Death Conditions Lotka and Lotka-Volterra Models... [Pg.467]

Staying within a class of mono- and bimolecular reactions, we thus can apply to them safely the technique of many-point densities developed in Chapter 5. To establish a new criterion insuring the self-organisation, we consider below the autowave processes (if any) occurring in the simplest systems -the Lotka and Lotka-Volterra models [22-24] (Section 2.1.1). It should be reminded only that standard chemical kinetics denies their ability to selforganisation either due to the absence of undamped oscillations (the Lotka model) or since these oscillations are unstable (the Lotka-Volterra model). [Pg.473]

To treat the stochastic Lotka and Lotka-Volterra models, we have now to extend the formalism presented in Section 2.2.2, where collective variables-numbers of particles iVA and Vg were used to describe reactions. The point is that this approach neglects local density fluctuations in small element volumes. To incorporate both these fluctuations and their correlations due to diffusive conjunction, we are in position now to reformulate these models in terms of the diffusion-controlled processes - in contrast to the rather primitive birth-death formalism used in Section 2.2.2. It permits also to demonstrate in the non-trivial way a role of diffusion in the autowave processes. The main results of this Chapter are published in [21, 25]. [Pg.473]

Let us reformulate the standard Lotka-Volterra model [23, 24] described by the set (2.1.27) in terms of the diffusion-controlled process as it was suggested for the first time by Kuzovkov [21, 25-27], Its basic elements are as follows. [Pg.473]

Since our principal aim in studying the Lotka-Volterra model is to clarify whether the limit cycle or chaotic regime could arise for this model, let us specify now the functions /za(r), /zb(r) and a(r) in a way simplifying the integral terms in (8.2.1) to (8.2.5). [Pg.476]

A set of equations (8.2.12) and (8.2.13) for the concentration dynamics is formally similar to the standard statement of the Lotka-Volterra model given... [Pg.478]

In other words, K(t) is afunctional of the joint correlation function of similar particles. In this respect, a set of equations (8.2.12) and (8.2.13) is similar to the stochastic treatment of the Lotka-Volterra model (equations (2.2.68) and (2.2.69)) considered in Section 2.3.1 using the similar time-dependent reaction rate (2.2.67). [Pg.479]

These two kinds of dynamics - for particle correlations and concentrations -become coupled through the reaction rate. The functionals J[Z] in (8.2.15) to (8.2.17) were defined in Chapter 5 (5.1.36) to (5.1.38) for different space dimensions d = 1,2,3. They emerge in those terms of (8.2.9) to (8.2.11) which are affected by the superposition approximation. It should be stressed that in the case of the Lotka-Volterra model it is the only approximation used for deriving the equations of the basic model. [Pg.479]


See other pages where Lotka-Volterra is mentioned: [Pg.789]    [Pg.92]    [Pg.93]    [Pg.93]    [Pg.93]    [Pg.93]    [Pg.93]    [Pg.93]    [Pg.94]    [Pg.94]    [Pg.317]    [Pg.254]    [Pg.255]    [Pg.61]    [Pg.63]    [Pg.99]    [Pg.100]    [Pg.104]    [Pg.473]    [Pg.473]    [Pg.473]    [Pg.475]    [Pg.477]    [Pg.477]    [Pg.479]   
See also in sourсe #XX -- [ Pg.215 , Pg.246 , Pg.248 , Pg.290 ]

See also in sourсe #XX -- [ Pg.343 ]




SEARCH



Chemical reaction Lotka-Volterra mechanism

Equations Lotka-Volterra

Generalised Lotka-Volterra models

Lotka

Lotka-Volterra analysis

Lotka-Volterra competition model

Lotka-Volterra mechanism

Lotka-Volterra model

Lotka-Volterra models competitive

Lotka-Volterra predator-prey model

Lotka-Volterra problem

Lotka-Volterra reaction

Lotka-Volterra system

Lotka-Volterra “prey-predator” interaction

Oscillation Volterra-Lotka type

Oscillations Lotka—Volterra mechanism

Prey-predator system Lotka—Volterra model

Stochastic Lotka-Volterra model

Sustained oscillations of the Lotka-Volterra type

The Lotka-Volterra model

The stochastic Lotka-Volterra model

Volterra

© 2024 chempedia.info