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Liquid chromatography circular dichroism

HPLC-CD High-pressure liquid chromatography-circular dichroism... [Pg.468]

Rosenzweig, Z. and Yeung, E. S., Laser-based double-beam circular dichroism detector for liquid chromatography, Appl. Spectr., 47, 207, 1993. [Pg.95]

Mancini, F., Fiori, J., Bertucci, C., Cavrini, V., Bragieri, M., Zanotti, M.C., Liverani, A., Borzatta, V., Andrisano, V. (2004). Stereoselective determination of allethrin by two-dimensional achiral/chiral liquid chromatography with ultraviolet/circular dichroism detection. J. Chromatogr. A 1046, 67-73. [Pg.342]

Optical Spectroscopy General principles and overview, 246, 13 absorption and circular dichroism spectroscopy of nucleic acid duplexes and triplexes, 246, 19 circular dichroism, 246, 34 bioinorganic spectroscopy, 246, 71 magnetic circular dichroism, 246, 110 low-temperature spectroscopy, 246, 131 rapid-scanning ultraviolet/visible spectroscopy applied in stopped-flow studies, 246, 168 transient absorption spectroscopy in the study of processes and dynamics in biology, 246, 201 hole burning spectroscopy and physics of proteins, 246, 226 ultraviolet/visible spectroelectrochemistry of redox proteins, 246, 701 diode array detection in liquid chromatography, 246, 749. [Pg.6]

Synovec, R.E. Yeung, E.S. Fluorescence detected circular dichroism as a detection principle in high-performance liquid chromatography. J. Chromatogr. 1986, 368, 85-93. [Pg.461]

Westwood, S.A. Games, D.E. Sheen, L. Use of circular dichroism as a high-performance liquid chromatography detector. Chromatography 1981, 204, 103-107. [Pg.461]

Zukowski, J. Tang, Y. Berthod, A. Armstrong, D.W. Investigation of a circular dichroism spectrophotometer as a liquid chromatography detector for enantiomers sensitivity, advantages, and limitations. Anal. Chim. Acta. 1992, 258, 83-92. [Pg.461]

Various techniques used in the investigations include enantioselective liquid chromatography, enantioselective H-NMR spectroscopy, polarimetry, and circular dichroism spectroscopy. This work offers a fundamental new outlook on transition states and on the relationship between the structures of photochromic compounds and the corresponding energy barriers of their ring-opening reactions. [Pg.7]

A. Mannschreck, On-line measurement of circular dichroism spectra during enantioselective liquid chromatography, Trends Anal. Chem. 12, 220-225 (1993) Chem. Abstr. 119, 194725 (1993). [Pg.294]

There are many other useful analytical methods. Chromatographic methods such as gas chromatography (GC) and high-performance liquid chromatography (HPLC) are used daily for identification and estimation of the purity of a synthetic product. Chiroptical methods, such as circular dichroism (CD) spectroscopy, are also important especially in studying the relationships between absolute configuration and bioactivity of biofunctional molecules. In later chapters I will give some examples of application of CD spectroscopy in enantioselective synthesis. [Pg.14]

Ac AIBN 9-BBN Bn Boc Bu Bz CAN Cbz CD CSA DABCO DAST DBN DBU DCC DDQ DEAD DHP DIAD DIBAL-H DMAP DME DMF DMP DMSO DNB EE Ee Eq Et Fmoc GLC HLADH HMDS HMPA HOBt HPLC Im acetyl 2,2/-azobisisobutyronitrile 9-borabicyclo[3.3.1]nonane benzyl f-butoxycarbonyl butyl benzoyl ceric ammonium nitrate benzyloxycarbonyl circular dichroism camphorsulfonic acid 1.4- diazabicyclo[2.2.2]octane A,A-Diethylaminosulfur trifluoride 1.5- diazabicyclo[4.3.0]non-5-ene l,8-diazabicyclo[5.4.0]undec-7-ene A,A -dicyclohexylcarbodiimide 2.3- dichloro-5,6-dicyano-1,4-benzoquinone diethyl azodicarboxylate 3.4- dihydro-2//-pyrane diisopropyl azodicarboxylate diisobutylaluminum hydride 4-A,A -dimethylaminopyridine 1,2-dimethoxyethane A,A -dimethylformamide Dess -Martin periodinane [1,1,1 -tris(acetyloxy)-1,1 -dihydro-1,2-benziodoxol-3-( IH) -one] dimethyl sulfoxide 3.5- dinitrobenzoyl 2-ethoxyethyl enantiomeric excess molar equivalent ethyl 9-fluorenylmethoxycarbonyl gas-liquid chromatography horse liver alcohol dehydrogenase 1,1,1,3,3,3 -hexamethyldisilazane hexamethylphosphoric triamide 1 -hydroxybenzotriazole high-performance liquid chromatography 1-imidazolyl or imidazole... [Pg.314]


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