Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Linear free eneigy relationships

Guengerich EP, Yun CH, Macdonald TL (1996) Evidence for a 1-electron oxidation mechanism in N-dealkylation of N, N-dialkylanilines by cytochrome P450 2B1. Kinetic hydrogen isotope effects, linear free eneigy relationships, comparisons with horseradish peroxidase, and studies with oxygen surrogates. J Biol Chem 271 27321-27329... [Pg.170]

Duckworth OW, Cygan RT, Martin ST (2004) Linear free eneigy relationships between dissolution rates and molecular modeling energies of rhombohedral carbonates. Langmuir 20 2938-2946... [Pg.528]

The a value measures the intrinsic reactivity of the complex, and measures how much the rate is affected by the or-donor strength of the ligand. The result is a Hammett-type linear free eneigy (LFE) relationship. Very bulky ligands show rates slower than predicted, however. [Pg.119]

See other pages where Linear free eneigy relationships is mentioned: [Pg.15]    [Pg.1234]    [Pg.15]    [Pg.1234]    [Pg.28]    [Pg.870]    [Pg.764]   
See also in sourсe #XX -- [ Pg.169 ]



SEARCH



Free eneigy

Linear relationship

Linearized relationship

© 2024 chempedia.info