Lifetime inherent

We found that the quantum confinement effect does not modify the emission lifetime inherent in bulk materials. Our results are at variance with those obtained by Bharghava et al. for ZnS Mn nanocrystals and partially agree with recent results by Bol et al. [5] and Chamano et al. [8]. 

Alternatively, weak acids and certain salts have been found to extend the lifetimes of inherently rapid reactions which occur with highly reactive esters, such as bis(2,4-dinitrophenyl) oxalate (95). A chemiluminescent demonstration based on the oxaUc ester reaction has been described (96) and the reaction has been developed iato a practical lighting system. 

Entry 3 has only alkyl substituents and yet has a significant lifetime in the absence of oxygen. The tris(/-butyl)methyl radical has an even longer lifetime, with a half-life of about 20 min at 25°C. The steric hindrance provided by the /-butyl substituents greatly retards the rates of dimerization and disproportionation of these radicals. They remain highly reactive toward oxygen, however. The term persistent radicals is used to describe these species, because their extended lifetimes have more to do with kinetic factors than with inherent stability." Entry 5 is a sterically hindered perfluorinated radical and is even more long-lived than similar alkyl radicals. 

A free radical (often simply called a radical) may be defined as a species that contains one or more unpaired electrons. Note that this definition includes certain stable inorganic molecules such as NO and NO2, as well as many individual atoms, such as Na and Cl. As with carbocations and carbanions, simple alkyl radicals are very reactive. Their lifetimes are extremely short in solution, but they can be kept for relatively long periods frozen within the crystal lattices of other molecules. Many spectral measurements have been made on radicals trapped in this manner. Even under these conditions, the methyl radical decomposes with a half-life of 10-15 min in a methanol lattice at 77 K. Since the lifetime of a radical depends not only on its inherent stabihty, but also on the conditions under which it is generated, the terms persistent and stable are usually used for the different senses. A stable radical is inherently stable a persistent radical has a relatively long lifetime under the conditions at which it is generated, though it may not be very stable. 

Although methods have been established to derive these levels (Barnes and Dourson 1988 EPA 1990c), uncertainties are associated with these techniques. Furthermore, ATSDR acknowledges additional uncertainties inherent in the application of the procedures to derive less than lifetime MRLs. As an example, acute inhalation MRLs may not be protective for health effects that are delayed in development or are acquired following repeated acute insults, such as h q)ersensitivity reactions, asthma, or chronic bronchitis. As these kinds of health effects data become available and methods to assess levels of significant human exposure improve, these MRLs will be revised. 

Experiments in rats (38) have shown that y irradiation decreases the inherent viscosity of lactide/glycolide copolymers and increases the biodegradation rate. The in vivo lifetime of a 92 8 DL-lactide/ glycolide copolymer was decreased from about 40 weeks to about 30 weeks after treatment with 2 Mrad of y irradiation. 

The energy q of a nuclear or electronic excited state of mean lifetime t cannot be determined exactly because of the limited time interval At available for the measurement. Instead, q can only be established with an inherent uncertainty, AE, which is given by the Heisenberg uncertainty relation in the form of the conjugate variables energy and time,... 

L. Matisova-Rychla and J. Rychly, Inherent relations of chemiluminescence and thermooxidation of polymers, In R.L. Clough, N.C. Billingham and K.T. Gillen (Eds.), Advances in Chemistry, Series 249 Polymer Durability, Degradation, Stabilization and Lifetime Prediction. American Chemical Society, Washington, DC, 1996, p. 175. 

It is important to note that if a mixture of fluorophores with different fluorescence lifetimes is analyzed, the lifetime computed from the phase is not equivalent to the lifetime computed from the modulation. As a result, the two lifetimes are often referred to as apparent lifetimes and should not be confused with the true lifetime of any particular species in the sample. These equations predict a set of phenomena inherent to the frequency domain measurement. 

The techniques of u.SR and p-LCR are based on the fact that parity is violated in weak interactions. Consequently, when a positive muon is created from stationary pion decay its spin is directed opposite to its momentum. This makes it possible to form a beam of low energy (4 MeV) positive muons with nearly 100% spin polarization at high intensity particle accelerators such as TRIUMF in Canada, the PSI in Switzerland, LAMPF and BNL in the USA, KEK in Japan, and RAL in England. Furthermore the direction of position emission from muon decay is positively correlated with the muon spin polarization direction at the time of decay. This allows the time evolution of the muon spin polarization vector in a sample to be monitored with a sensitivity unparalleled in conventional magnetic resonance. For example, only about 101 7 muon decay events are necessary to obtain a reasonable signal. Another important point is that //.SR is conventionally done such that only one muon is in the sample at a time, and for p,LCR, even with the highest available incident muon rates, the 2.2 fis mean lifetime of the muon implies that only a few muons are present at a given time. Consequently, muonium centers are inherently isolated from one another. 

The photochemistry of [26] was first studied by Breslow and Winnik (1969). The excited triplet state undergoes intramolecular hydrogen abstraction which quenches the excited state and shortens the triplet lifetime. Here cyclisation involves the chain interior, each CH2 group being inherently... 

These kinds of benefits can be realized over the entire lifetime of a facility. Selecting and implementing an inherently safer option is generally much less costly and more feasible at the concept and development stages of a new process, as compared to implementing fundamental changes to an existing facility. 

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