KINETICS OF SORPTION IN BATCH SYSTEMS

Kinetics of Sorption in Batch Systems Linear Equilibrium... 

In batch systems, the distribution or sorption coefficient (Xliquid phases. The X(j is commonly measured under equilibrium or at least steady-state conditions, unless the goal of the experiment is to examine the kinetics of sorption. It is defined as follows ... 

By combining thermodynamically-based monomer partitioning relationships for saturation [170] and partial swelling [172] with mass balance equations, Noel et al. [174] proposed a model for saturation and a model for partial swelling that could predict the mole fraction of a specific monomer i in the polymer particles. They showed that the batch emulsion copolymerization behavior predicted by the models presented in this article agreed adequately with experimental results for MA-VAc and MA-Inden (Ind) systems. Karlsson et al. [176] studied the monomer swelling kinetics at 80 °C in Interval III of the seeded emulsion polymerization of isoprene with carboxylated PSt latex particles as the seeds. The authors measured the variation of the isoprene sorption rate into the seed polymer particles with the volume fraction of polymer in the latex particles, and discussed the sorption process of isoprene into the seed polymer particles in Interval III in detail from a thermodynamic point of view. 

Arnold, W. A. Roberts, A. L. (2000) Pathways and Kinetics of Chlorinated Ethylene and Chlorinated Acetylene Reaction with Fe(0) Particles. Environ. Sci. Technol. 34(9), 1794—1805. Burris, D. R. Campbell, T. X Manoranjan, V. S. (1995) Sorption of Trichloroethene and Tetra-chloroethene in a batch reactive metallic iron-water system. Environ. Sci. Technol. 29,... 

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