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Kinetics of cellulose deterioration

Feller RL, Lee SB, Bogaard J (1986) The kinetics of cellulose deterioration. In Needles HL, Zeronian SH (eds) Historic Textile and Paper Materials Conservation and Characterization. Advances in Chemistry Series 212. ACS, Washington DC, p 329... [Pg.44]

Acid-catalyzed hydrolytic degradation of cellulose proceeds according to the principles of chemical kinetics. Nonetheless, concepts of kinetics have not been widely applied in the literature concerning the conservation of cellulosic materials. Thirty years ago, McBurney (I) provided an excellent exposition of this subject. We will review the subject in the light of developments since that time (2) and will present examples from the literature and from our own work to illustrate ways in which an analysis of the kinetics of chain scission can help conservators better understand the deterioration of cellulose-based materials. [Pg.322]

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