Kinetics and mechanisms for

J. W. Moore and R. G. Pearson, Kinetics and Mechanism, 3rd ed., Wiley-Interscience, New York, 1981. The first edition by A. A. Frost and R. G. Pearson appeared ia 1953 and the second edition by the latter authors appeared ia 1961. Probably the best known graduate text ia the United States that treats kinetics and mechanisms for general chemistry. 

Nelson L, I Shanahan, HW Sidebottom, J Treacy, OJ Nielsen (1990) Kinetics and mechanism for the oxidation of 1,1,1-trichloroethane. Int J Chem Kinet 22 577-590. 

Cabelli, D.E. and Bielski, B. (1983). Kinetics and mechanism for the oxidation of ascorbic acid (ascorbate by HO2/O2 radicals. A pulse radiolysis and stopped-flow photolysis study. J. Phys. Chem. 87, 1809. 

Reaction kinetics and mechanisms for oxidation of [Fe(diimine)2(CN)2], [Fe(diimine)(CN)4] (diimine = bipy or phen) (and indeed [Fe(CN)6] ) by peroxoanions such as (S20g, HSOs", P20g ) have been reviewed. Reactivity trends have been established, and initial state— transition state analyses carried out, for peroxodisulfate oxidation of [Fe(bipy)2(CN)2], [Fe(bipy)(CN)4] , and [Fe(Me2bsb)(CN)4] in DMSO—water mixtures. Whereas in base hydrolysis of iron(II)-diimine complexes reactivity trends in binary aqueous solvent mixtures are generally determined by hydroxide solvation, in these peroxodisulfate oxidations solvation changes for both partners affect the observed pattern. ... 

The kinetics and mechanism for oxygen transfer between 4-cyano-V,V,-dimethylaniline V-oxide and a C2-capped mexo-tetraphenylporphyrinatoiron(III) and mc5 o-tetrakis(pentafiuorophenyl)-porphyrinatoiron(III) have been established. Addition of a copper(II) porphyrin cap to an iron(II)-porphyrin complex has the expected effect of reducing both the affinities and rate constants for addition of dioxygen or carbon monoxide. These systems were studied for tetradecyl-substituted derivatives solubilized by surfactants such as poly(ethylene oxide) octaphenyl ether. ... 

Wallington, T. J P. Dagaut, and M. J. Kurylo, Ultraviolet Absorption Cross Sections and Reaction Kinetics and Mechanisms for Peroxy Radicals in the Gas Phase, Chem. Rev., 92, 667-710 (1992). 

Brodzinsky, R., S. G. Chang, S. S. Markowitz, and T. Novakov, Kinetics and Mechanism for the Catalytic Oxidation of Sulfur Dioxide on Carbon in Aqueous Suspensions, J. Phys. Chem., 84, 3354-3358 (1980). 

Kinetics and Mechanism for HO + CO. Atmospheric interest in the HO + CO reaction stems from its well-recognized role as the sole process for converting CO to C02. Although this reaction is among the most extensively studied gas phase free radical reactions, a detailed understanding of its kinetics and mechanism is still lacking. Presumably, it is not a simple elementary reaction but most likely involves an addition complex which can yield HOO and C02 in the presence of 02, e.g.,... 

M. Kalman, J. Socolowski, and J. Szafranek, Kinetic and mechanism for the epimerisation of aldopentonic acid potassium salts in aqueous alkali, J. Carbohydr. Chem., 6 (1987) 587-592. 

Modelling of kinetic dependences. Calculation of steady state kinetic dependences according to the model (4)-(5) cannot be performed without knowing the rate constants. Let us use the parameters (Table 6) for the two-route mechanism (1), the complete set of which was first given by Cassuto et al. [49]. The kinetics and mechanism for CO oxidation over polycrystalline platinum were studied [48] using the molecular beam technique. 

Whereas only a few examples have been discussed here, it is obvious that the exact kinetics and mechanisms for Fenton oxidations are highly depen-... 

E. Glickman, K. Sarychev, V. Demin and Y. Goryounov, Fracture kinetics and mechanism for Cu under deformation in surface-active melts, Communication IV The LME macroscopic manifestations and micromechanism, Soviet Physics Journal, 7, 2-29, 1976 (in Russian). 

The kinetics and mechanism for photochemical rearrangement of pyrazine 1,4-dioxide (41) into 5-hydroxy-2(l//)-pyrazinonc (42) have been studied.869... 

Atkinson, R. (1991) Kinetics and mechanisms for the gas-phase reactions of the NO3 radical with organic compounds. J. Phys. Chem. Ref Data 20(2), 459-507. 

The kinetics and mechanism for the oxidation of As(III) by [Mo(CN)g] (88) and [W(CN)g] (89) in alkaline medium showed a first-order dependence on [OH ] and alkali metal ion concentrations, respectively. The hdyroxide dependence is related to the tribasic character of As(OH)3 and, depending on the alkalinity range of the investigation, will determine which active As(III) species in Eqs. (80-81) will function in the mechanism. 

Oivanen M, Kuusela S, Lonnberg H. Kinetics and mechanism for 37. the cleavage and isomerization of phosphodiester bonds of RNA... 

Caution should be suggested against using this or any other effect as a cure-all for octahedral kinetics and mechanisms. For example, steric hindrance can change a planar d system, which normally reacts by a bimolecular path 18) to unimolecular reactivity 11, 93). (On the other hand, even the concept of molecularity in complex ion reactions has been questioned by Adamson 3) who initiated and made good use of the Stv 2FS path 2, 4)- Some of the manifestations of this problem have been discussed by others as well 68, 90).)... 

H. Niki, P. D. Maker, C. M. Savage, L. P. Breitenbach, A long-path Fourier transform infrared study of the kinetics and mechanism for OH radical initiated oxidation of dimethyl mercury, J. Phys. Chem., 87 (1983), 4978 981. 

Wamser, C. C., and J. A. Yates, Kinetics and Mechanisms for the Two-Phase Reaction Between Aqueous Aniline and Benzoyl Chloride in Chloroform, with and without Pyridine Catalysis, J. Org. Chem., 54, 150 (1989). 

Towards reliable prediction of kinetics and mechanisms for elementary processes Key combustion initiation reactions of ammonium perchlorate... 

The kinetics and mechanisms for reactions of H and HO with HCIO4, important elementary processes in the early stages of the AP combustion reaction, have not been studied experimentally or theoretically. The mechanisms for these reactions and their rate constants are presented below. 

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