Iron oxide-mica

Iron Oxide-Mica. Iron(III) oxide is suitable, like titanium dioxide, for coating of mica platelets. It combines a high refractive index (metallic luster) with good hiding power and weather resistance. 

It is also possible to produce iron oxide mica pigments by a direct CVD fluidized bed process where iron pentacarbonyl is oxidized and Fe203 is deposited on the mica surface [5.227] ... 

Fundal (1996), refining his previously published calculations and suiiunarizing the variable effects of each of the common moduli, presented an updated equation to calculate the free lime (AFC) from laboratory testing of the raw feed at 1400 , 1450 , and 1500°C, taking into account some of the variables making up A,, namely, the percentages of dolomite and flux minerals >45pm, such as iron oxides, mica, and AKOH). Fundal s new equation for a 1400°C free lime calculation is ... 

The disadvantage of this procedure is that the minerals maybe physically or chemically altered during burning. Eor example, the refractive index of clay minerals is changed the color, birefringence, and pleochroism of micas is altered carbonates are destroyed and the iron sulfides are oxidized to iron oxides. 

A U.S. Bureau of Mines survey covering 202 froth flotation plants in the United States showed that 198 million tons of material were treated by flotation in 1960 to recover 20 million tons of concentrates which contained approximately 1 billion in recoverable products. Most of the worlds copper, lead, zinc, molybdenum, and nickel are produced from ores that are concentrated first by flotation. In addition, flotation is commonly used for the recoveiy of fine coal and for the concentration of a wide range of mineral commodities including fluorspar, barite, glass sand, iron oxide, pyrite, manganese ore, clay, feldspar, mica, sponumene, bastnaesite, calcite, garnet, kyanite, and talc. 

Clays occur naturally either in a relatively pure condition or mixed with other materials and they are therefore classified into one of two large groups primary and secondary clays. Primary clays are quite pure, uncontaminated by other materials, and have a rather uniform composition. Secondary clays are mixtures of clay with other minerals such as quartz, talc, mica, iron oxides, and even organic matter (the latter derived from the decay of dead plants and animals) the particles of most of the contaminating materials are generally of similar size to those of the clay (Kingery et al. 1976). 

The presence of mica in pearlescent pigments only partly accounts for the appearance of the pigment. A very thin layer of the inorganic oxide titanium dioxide (TiC>2) or iron oxide (Fe2C>3) or both is coated on the mica platelets. The various colors and pearlescent effects are created as light is both refracted and reflected from the titanium dioxide layers. The very thin platelets are highly reflective and transparent. With their plate-like shape, the platelets are easily oriented into parallel layers as the paint medium is applied. Some of the incident light is reflected... 

A number of clays are layered silicate-like materials. Most clays contain finely divided quartz, micas, and feldspars. Iron oxide-rich clays are employed to make pottery and terracotta articles. Clays containing iron oxide and sand are used to make bricks and tiles. Clays rich in calcium and magnesium carbonate are known as marls and are used in the cement industry (Section 12.2). 

Thermal decomposition of iron pentacarbonyl. Very finely divided red iron oxide is obtained by atomizing iron pentacarbonyl, Fe(CO)5, and burning it in excess of air. The size of the particles depends on the temperature (580-800 °C) and the residence time in the reactor. The smallest particles are transparent and consist of 2-line ferri-hydrite, whereas the larger, semi-transparent particles consist of hematite (see Chap. 19). The only byproduct of the reaction is carbon dioxide, hence, the process has no undesirable environmental side effects. Magnetite can be produced by the same process if it is carried out at 100-400 °C. Thermal decomposition of iron pentacarbonyl is also used to coat aluminium powder (in a fluidized bed) and also mica platelets with iron oxides to produce interference or nacreous pigments. 

Kaolin clays are naturally occuring sedimentary deposits composed largely of kaolinite mineral. Typical impurities in these deposits are iron oxides, titanifer-ous minerals, silica, feldspar, mica, sulfides and organic matter. The majority of kaolin clay produced in the world is used in the paper industry as coating and filler materials. This mineral also makes an excellent filler, carrier, opacifier and diluent in a variety of industrial products such as paints, plastics, cement, rubber, pharmaceuticals, etc. 

Figure 17. Proposed phase relations where K is a mobile component and Al, Fe are immobile components at about 20°C and several atmosphere water pressure for aluminous and ferric-ferrous mica-smectite minerals. Symbols are as follows I illite G = non-expanding glauconite Ox = iron oxide Kaol = kaolinlte Mo montmorillonite smectite N nontronitic smectite MLAL aluminous illite-smectite interlayered minerals Mlpe = iron-rich glauconite mica-smectite interlayered mineral. Dashed lines 1, 2, and 3 indicate the path three different starting materials might take during the process of glauconitization. The process involves increase of potassium content and the attainment of an iron-rich octahedral layer in a mica structure.

In principle, all lamellar minerals may be used as barrier pigments, e.g., micaceous iron oxide [5.167]-[5.169], layer silicates (mica), linear polymeric silicates (wollas-tonite), and talc [5.170], However, untreated mica and talc are not very suitable because they are highly permeable to water [5.57]. The surface can be modified with, for example, silanes or titanates, to reduce water permeability and improve adhesion... 

Table LXVI shows the correlation coefficients obtained for the hard and soft types. The existence of two clay populations limits the meaning of correlations found for the combined data (Hinckley, 1961). In both groups K20 and mica and K20 and Fe203 are positively correlated. In addition, for the soft type there is a positive correlation between Fe203 and mica and negative correlations between mica and books, and Fe203 and books. These interrelations suggest, but do not prove, that books are derived from the mica and that much of the K20 and Fe203 may be present in the mica or that a leaching process that altered the mica and removed its interlayer K20 also removed the iron regardless of where it occurred (pyrite, anatase, iron oxides, etc.).

Fillers used in large quantities to reinforce plastics are alumina (aluminum oxide), calcium carbonate, calcium silicate, cellulose flock, cotton (different forms), short glass fiber, glass beads, glass spheres, graphite, iron oxide powder, mica, quartz, sisal, silicon carbide, dtanium oxide, and tungsten carbide. Choice of filler varies and depends to a great extent upon the requirements of the end item and method of fabrication. 

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