Iron nuclear

Mossbauer spectroscopy has been used to characterize the iron clusters in fuscoredoxin isolated from D. desulfuricans (133). The authors explained why the iron nuclearity was incorrectly determined, and studied the protein in three different oxidation states fully oxidized, one-electron reduced, and two-electron reduced. The error made in determining the iron cluster nuclearity was caused by the assumption that in the as-purified fuscoredoxin, cluster 2 is in a pure S = state. This assumption was proven to be false and unnecessary. In fact, the observation of four resolved, equal intensity (8% of total Fe absorption) spectral components associated with the S = i species in the as-purified protein is consistent with cluster 2 being a tetranuclear Fe cluster. The 4x8 = 32% Fe absorption for the four components indicates that only 64% of clusters 2 are in the S = state (the total Fe absorption for cluster 2 is 50% of the total Fe absorption). The remaining clusters 2 are in a different oxidation state, the spectrum of which is unresolved from that of cluster 1. 

J. Bloch, Effect of neutron irradiation of uranium-iron alloys dilute in iron, . /. Nuclear Mater. 6 (1962) 203-212. 

Perkins, R. W., Procedure in Nielsen, J. M., "The Radio-chemistry of Iron," Nuclear Science Series Report, NAS-NS-3017, 25 (i960). 

Ironically, nuclear transmutations were taking place virtually under the noses of the alchemists (or nnder their feet), bnt they had neither the methods to detect nor the knowledge to use these happenings. The discovery of the nuclear transmutation process was closely linked to the discovery of radioactivity by Henri Becqnerel in 1896. Nnclear transmutations occnr dnring the spontaneous radioactive decay of naturally occurring thorium and uranium (atomic numbers 90 and 92, respectively) and the radioactive... 

The many attempts at lattice-sum calculations of the electric field gradient tensor have already been listed in Section 5.4 in connection with the evaluation of the iron nuclear quadrupole moment. 

MS Mossbauer Spectroscopy [233-236] Chemical shift of nuclear energy states, usually of iron Chemical state of atoms... 

Alloys with other useful properties can be obtained by using yttrium as an additive. The metal can be used as a deoxidizer for vanadium and other nonferrous metals. The metal has a low cross section for nuclear capture. 90Y, one of the isotopes of yttrium, exists in equilibrium with its parent 90Sr, a product of nuclear explosions. Yttrium has been considered for use as a nodulizer for producing nodular cast iron, in which the graphite forms compact nodules instead of the usual flakes. Such iron has increased ductility. 

Sodium and chloride may be measured using ion-selective electrodes (see Electro analytical techniques). On-line monitors exist for these ions. Sihca and phosphate may be monitored colorimetricaHy. Iron is usually monitored by analysis of filters that have had a measured amount of water flow through them. Chloride, sulfate, phosphate, and other anions may be monitored by ion chromatography using chemical suppression. On-line ion chromatography is used at many nuclear power plants. 

Because of its low neutron absorption, zirconium is an attractive stmctural material and fuel cladding for nuclear power reactors, but it has low strength and highly variable corrosion behavior. However, ZircaHoy-2, with a nominal composition of 1.5 wt % tin, 0.12 wt % iron, 0.05 wt % nickel, 0.10 wt % chromium, and the remainder zirconium, can be used ia all nuclear power reactors that employ pressurized water as coolant and moderator (see... 

The largest consumers of water in the United States are thermal power plants (eg, steam and nuclear power plants) and the iron and steel, pulp and paper, petroleum refining, and food-processing industries. They consume >60% of the total industrial water requirements (see also Power generation Wastes, industrial). 

Kem-eisen, n. mottled white pig iron (Elec.) core iron, -eiweisskorper, -eiweisstoff, m. nucleoprotein. -farbe,/., -f bemlttel, n., -farbstoff, m. nuclear stain, -f bung, /, Micros.) nuclear staining, -faser, /. nuclear fiber or filament. 

Th ese manufactured light sources are, perhaps ironically, largely dependent on the Sun. The radiant energy from the Sun has been stored in the fossilized remains of billions of creatures over millions of years and is used to power the electric light sources created by modern humans. The power generated by hydroelectric sources also is a result of solar evaporation and subsequent rainfall. Only nuclear reactors provide power independent of the Sun, which is, of course, the largest nuclear reactor in the solar system. 

Deep-bed condensate polishers are commonly used for nuclear reactor power plants. Due to the extreme operating conditions, the resin is sometimes taken out of service as frequently as every 3 weeks for ultrasonic cleaning. This process removes the iron oxides and other particulates filtered out by the resin media. 

Where an alkaline EDTA cleaning program is employed, hydrazine sometimes is added to help keep the chelated iron in the ferrous state and prevent corrosion of exposed steel. Under very exacting circumstances, such as removing iron oxides from nuclear powered SGs, triammonium EDTA together with 0.5 M hydrazine may be employed, at a pH of 7 and a temperature of 200 °F (93 °C). 

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