Iron chloride oxide intercalate with pyridine

FeB4C 2H]o, [1,1 -commo-Bis(2,3-dicaiba-l-ferra-c/oso-heptaborane)](12), 2,2, 3,3 -tetraethyl-1,1 -dihydro-, 22 215 FeCIO, Iron chloride oxide, intercalate with 4-aminopyridine (4 1), 22 86 intercalate with pyridine (4 1), 22 86 intercalate with 2,4,6-trimethylpyridine (6 1), 22 86... 

The layered compound iron(lll) chloride oxide FeOCl absorbs pyridine derivative molecules into its van der Waals gap forming the intercalation compounds FeOCl (pyridine derivative), . Iron(III) chloride oxide and the pyridine derivatives act, respectively, as a Lewis acid and base in the reaction with a partial transfer of the pyridine derivative electrons to the host FeOCl layer. Electrical resistivity of the host FeOCl decreases from 107 2-cm to 103 J2-cm with intercalation, and the interlayer distance expands to almost twice the original value. 

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See also in sourсe #XX -- [ , , ]

See also in sourсe #XX -- [ , , ]

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