Ionic organic-inorganic hybrid materials

Liu YH, Sun XQ, Luo F et al (2007) Ionic liquids and cyanex 923-doped organic-inorganic hybrid materials for Y(III) and leuitheuiides (III) separation. Chinese J Rare Met 31 395-398... 

Coleman, F., Feng, G., Murphy, R.W., Nockemann, R, Seddon, K.R. and Swadzba-Kwasny, M., Lead(II) chloride ionic liquids and organic/inorganic hybrid materials - a study of chloroplumbate(ii) speciation, Dalton Trans. 42, 5025-5035 (2013). 

Dragan, E. S. Cazacu, M. Nistor, A., Ionic Organic/Inorganic Materials. III. Stimuli Responsive Hybrid Hydrogels Based on 01igo(N,N-dimethylamino-ethylmethacrylate) and Chloroalkyl-Functionalized Siloxanes. J. Polym. Sci., Part A Polym. Chem. 2009,47, 6801-6813. 

The nature of the solvent is an important parameter in hybrid synthesis, especially as it can sometimes be problematic to identify a solvent that is suitable for both the inorganic and the organic reactants. Obviously, the use of non-aqueous or mixed solvents has been widely adopted, just as it has in the case of purely inorganic frameworks, and the use of immiscible biphasic solvents,18 whereby the products form at the solvent interface, is an interesting strategy. Ionic liquids, which have been shown to be effective in the synthesis of inorganic framework materials,62 are just starting to be applied to hybrid frameworks.63... 

---